Design and synthesis of C(3)-symmetric molecules bearing propellane moieties via cyclotrimerization and a ring-closing metathesis sequence

We have developed an efficient synthetic strategy to assemble C(3)-symmetric molecules containing propellane moieties as end groups and a benzene ring as a central core. The synthesis of these C(3)-symmetric molecules involves simple starting materials. Our approach to C(3)-symmetric compounds relie...

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Autores principales: Kotha, Sambasivarao, Todeti, Saidulu, Aswar, Vikas R
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2018
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6204777/
https://www.ncbi.nlm.nih.gov/pubmed/30410614
http://dx.doi.org/10.3762/bjoc.14.230
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author Kotha, Sambasivarao
Todeti, Saidulu
Aswar, Vikas R
author_facet Kotha, Sambasivarao
Todeti, Saidulu
Aswar, Vikas R
author_sort Kotha, Sambasivarao
collection PubMed
description We have developed an efficient synthetic strategy to assemble C(3)-symmetric molecules containing propellane moieties as end groups and a benzene ring as a central core. The synthesis of these C(3)-symmetric molecules involves simple starting materials. Our approach to C(3)-symmetric compounds relies on a Diels–Alder reaction, cyclotrimerization and ring-closing metathesis as key steps.
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spelling pubmed-62047772018-11-08 Design and synthesis of C(3)-symmetric molecules bearing propellane moieties via cyclotrimerization and a ring-closing metathesis sequence Kotha, Sambasivarao Todeti, Saidulu Aswar, Vikas R Beilstein J Org Chem Full Research Paper We have developed an efficient synthetic strategy to assemble C(3)-symmetric molecules containing propellane moieties as end groups and a benzene ring as a central core. The synthesis of these C(3)-symmetric molecules involves simple starting materials. Our approach to C(3)-symmetric compounds relies on a Diels–Alder reaction, cyclotrimerization and ring-closing metathesis as key steps. Beilstein-Institut 2018-10-01 /pmc/articles/PMC6204777/ /pubmed/30410614 http://dx.doi.org/10.3762/bjoc.14.230 Text en Copyright © 2018, Kotha et al. https://creativecommons.org/licenses/by/4.0https://www.beilstein-journals.org/bjoc/termsThis is an Open Access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc/terms)
spellingShingle Full Research Paper
Kotha, Sambasivarao
Todeti, Saidulu
Aswar, Vikas R
Design and synthesis of C(3)-symmetric molecules bearing propellane moieties via cyclotrimerization and a ring-closing metathesis sequence
title Design and synthesis of C(3)-symmetric molecules bearing propellane moieties via cyclotrimerization and a ring-closing metathesis sequence
title_full Design and synthesis of C(3)-symmetric molecules bearing propellane moieties via cyclotrimerization and a ring-closing metathesis sequence
title_fullStr Design and synthesis of C(3)-symmetric molecules bearing propellane moieties via cyclotrimerization and a ring-closing metathesis sequence
title_full_unstemmed Design and synthesis of C(3)-symmetric molecules bearing propellane moieties via cyclotrimerization and a ring-closing metathesis sequence
title_short Design and synthesis of C(3)-symmetric molecules bearing propellane moieties via cyclotrimerization and a ring-closing metathesis sequence
title_sort design and synthesis of c(3)-symmetric molecules bearing propellane moieties via cyclotrimerization and a ring-closing metathesis sequence
topic Full Research Paper
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6204777/
https://www.ncbi.nlm.nih.gov/pubmed/30410614
http://dx.doi.org/10.3762/bjoc.14.230
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