Precursors for Atmospheric Plasma‐Enhanced Sintering: Low‐Temperature Inkjet Printing of Conductive Copper

Bidentate diamine and amino‐alcohol ligands have been used to form solid, water‐soluble, and air‐stable monomeric copper complexes of the type [Cu(NH(2)CH(2)CH(R)Y)(2)(NO(3))(2)] (1, R=H, Y=NH(2); 2, R=H, Y=OH; 3, R=Me, Y=OH). The complexes were characterized by elemental analysis, mass spectrometry...

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Detalles Bibliográficos
Autores principales: Knapp, Caroline E., Metcalf, Elizabeth A., Mrig, Shreya, Sanchez‐Perez, Clara, Douglas, Samuel. P., Choquet, Patrick, Boscher, Nicolas D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6208189/
https://www.ncbi.nlm.nih.gov/pubmed/30402374
http://dx.doi.org/10.1002/open.201800131
Descripción
Sumario:Bidentate diamine and amino‐alcohol ligands have been used to form solid, water‐soluble, and air‐stable monomeric copper complexes of the type [Cu(NH(2)CH(2)CH(R)Y)(2)(NO(3))(2)] (1, R=H, Y=NH(2); 2, R=H, Y=OH; 3, R=Me, Y=OH). The complexes were characterized by elemental analysis, mass spectrometry, infrared spectroscopy, thermal gravimetric analysis, and single‐crystal X‐ray diffraction. Irrespective of their decomposition temperature, precursors 1–3 yield highly conductive copper features [1.5×10(−6) Ω m (±5×10(−7) Ω m)] upon atmospheric‐pressure plasma‐enhanced sintering.

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