Cargando…

Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation

In order to prepare parabolic superhydrophobic materials, copper meshes were used as the substrate and ultrasonic etching and oxidative corrosion were carried out with FeCl(3) solution and H(2)O(2) solution, respectively, and then the surface was modified with stearic acid (SA). The topological stru...

Descripción completa

Detalles Bibliográficos
Autores principales: Qiao, Xiaoying, Yang, Chunyan, Zhang, Qian, Yang, Shengke, Chen, Yangyang, Zhang, Dan, Yuan, Xiaoyu, Wang, Wenke, Zhao, Yaqian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6213289/
https://www.ncbi.nlm.nih.gov/pubmed/30304798
http://dx.doi.org/10.3390/ma11101914
_version_ 1783367733892612096
author Qiao, Xiaoying
Yang, Chunyan
Zhang, Qian
Yang, Shengke
Chen, Yangyang
Zhang, Dan
Yuan, Xiaoyu
Wang, Wenke
Zhao, Yaqian
author_facet Qiao, Xiaoying
Yang, Chunyan
Zhang, Qian
Yang, Shengke
Chen, Yangyang
Zhang, Dan
Yuan, Xiaoyu
Wang, Wenke
Zhao, Yaqian
author_sort Qiao, Xiaoying
collection PubMed
description In order to prepare parabolic superhydrophobic materials, copper meshes were used as the substrate and ultrasonic etching and oxidative corrosion were carried out with FeCl(3) solution and H(2)O(2) solution, respectively, and then the surface was modified with stearic acid (SA). The topological structure and surface wettability of the prepared mesh were characterized by fluorescence microscope, scanning electron microscopy and contact angle measurement. Finally, the as-prepared copper meshes were applied to oil-water separation. The results showed that the micro-nano-mastoid structure on the surface of the copper mesh was flaky bulges, forming a rough structure similar to a paraboloid. When the oxidative corrosion time of H(2)O(2) was 1 min, it is more beneficial to increase the hydrophobicity of the surface of the copper mesh and increase the contact angle of water droplets on the surface of the membrane. Additionally, based on superhydrophobic materials of the parabolic copper mesh, the static contact angles of the water droplets, engine oil and carbon tetrachloride with the surface were approximately 153.6°, 5° and 0.1°, respectively and the sliding angle of the water droplets with the surface were approximately 4.9°. The parabolic membrane was applied to discuss the separation efficiency of different oils with deionized water and the separation efficiency was obtained as benzene > carbon tetrachloride > oil > machine oil. Therefore, based on the research, the parabolic superhydrophobic material has good efficiency of oil-water separation.
format Online
Article
Text
id pubmed-6213289
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-62132892018-11-14 Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation Qiao, Xiaoying Yang, Chunyan Zhang, Qian Yang, Shengke Chen, Yangyang Zhang, Dan Yuan, Xiaoyu Wang, Wenke Zhao, Yaqian Materials (Basel) Article In order to prepare parabolic superhydrophobic materials, copper meshes were used as the substrate and ultrasonic etching and oxidative corrosion were carried out with FeCl(3) solution and H(2)O(2) solution, respectively, and then the surface was modified with stearic acid (SA). The topological structure and surface wettability of the prepared mesh were characterized by fluorescence microscope, scanning electron microscopy and contact angle measurement. Finally, the as-prepared copper meshes were applied to oil-water separation. The results showed that the micro-nano-mastoid structure on the surface of the copper mesh was flaky bulges, forming a rough structure similar to a paraboloid. When the oxidative corrosion time of H(2)O(2) was 1 min, it is more beneficial to increase the hydrophobicity of the surface of the copper mesh and increase the contact angle of water droplets on the surface of the membrane. Additionally, based on superhydrophobic materials of the parabolic copper mesh, the static contact angles of the water droplets, engine oil and carbon tetrachloride with the surface were approximately 153.6°, 5° and 0.1°, respectively and the sliding angle of the water droplets with the surface were approximately 4.9°. The parabolic membrane was applied to discuss the separation efficiency of different oils with deionized water and the separation efficiency was obtained as benzene > carbon tetrachloride > oil > machine oil. Therefore, based on the research, the parabolic superhydrophobic material has good efficiency of oil-water separation. MDPI 2018-10-09 /pmc/articles/PMC6213289/ /pubmed/30304798 http://dx.doi.org/10.3390/ma11101914 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Qiao, Xiaoying
Yang, Chunyan
Zhang, Qian
Yang, Shengke
Chen, Yangyang
Zhang, Dan
Yuan, Xiaoyu
Wang, Wenke
Zhao, Yaqian
Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation
title Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation
title_full Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation
title_fullStr Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation
title_full_unstemmed Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation
title_short Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation
title_sort preparation of parabolic superhydrophobic material for oil-water separation
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6213289/
https://www.ncbi.nlm.nih.gov/pubmed/30304798
http://dx.doi.org/10.3390/ma11101914
work_keys_str_mv AT qiaoxiaoying preparationofparabolicsuperhydrophobicmaterialforoilwaterseparation
AT yangchunyan preparationofparabolicsuperhydrophobicmaterialforoilwaterseparation
AT zhangqian preparationofparabolicsuperhydrophobicmaterialforoilwaterseparation
AT yangshengke preparationofparabolicsuperhydrophobicmaterialforoilwaterseparation
AT chenyangyang preparationofparabolicsuperhydrophobicmaterialforoilwaterseparation
AT zhangdan preparationofparabolicsuperhydrophobicmaterialforoilwaterseparation
AT yuanxiaoyu preparationofparabolicsuperhydrophobicmaterialforoilwaterseparation
AT wangwenke preparationofparabolicsuperhydrophobicmaterialforoilwaterseparation
AT zhaoyaqian preparationofparabolicsuperhydrophobicmaterialforoilwaterseparation