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Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation
In order to prepare parabolic superhydrophobic materials, copper meshes were used as the substrate and ultrasonic etching and oxidative corrosion were carried out with FeCl(3) solution and H(2)O(2) solution, respectively, and then the surface was modified with stearic acid (SA). The topological stru...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6213289/ https://www.ncbi.nlm.nih.gov/pubmed/30304798 http://dx.doi.org/10.3390/ma11101914 |
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author | Qiao, Xiaoying Yang, Chunyan Zhang, Qian Yang, Shengke Chen, Yangyang Zhang, Dan Yuan, Xiaoyu Wang, Wenke Zhao, Yaqian |
author_facet | Qiao, Xiaoying Yang, Chunyan Zhang, Qian Yang, Shengke Chen, Yangyang Zhang, Dan Yuan, Xiaoyu Wang, Wenke Zhao, Yaqian |
author_sort | Qiao, Xiaoying |
collection | PubMed |
description | In order to prepare parabolic superhydrophobic materials, copper meshes were used as the substrate and ultrasonic etching and oxidative corrosion were carried out with FeCl(3) solution and H(2)O(2) solution, respectively, and then the surface was modified with stearic acid (SA). The topological structure and surface wettability of the prepared mesh were characterized by fluorescence microscope, scanning electron microscopy and contact angle measurement. Finally, the as-prepared copper meshes were applied to oil-water separation. The results showed that the micro-nano-mastoid structure on the surface of the copper mesh was flaky bulges, forming a rough structure similar to a paraboloid. When the oxidative corrosion time of H(2)O(2) was 1 min, it is more beneficial to increase the hydrophobicity of the surface of the copper mesh and increase the contact angle of water droplets on the surface of the membrane. Additionally, based on superhydrophobic materials of the parabolic copper mesh, the static contact angles of the water droplets, engine oil and carbon tetrachloride with the surface were approximately 153.6°, 5° and 0.1°, respectively and the sliding angle of the water droplets with the surface were approximately 4.9°. The parabolic membrane was applied to discuss the separation efficiency of different oils with deionized water and the separation efficiency was obtained as benzene > carbon tetrachloride > oil > machine oil. Therefore, based on the research, the parabolic superhydrophobic material has good efficiency of oil-water separation. |
format | Online Article Text |
id | pubmed-6213289 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-62132892018-11-14 Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation Qiao, Xiaoying Yang, Chunyan Zhang, Qian Yang, Shengke Chen, Yangyang Zhang, Dan Yuan, Xiaoyu Wang, Wenke Zhao, Yaqian Materials (Basel) Article In order to prepare parabolic superhydrophobic materials, copper meshes were used as the substrate and ultrasonic etching and oxidative corrosion were carried out with FeCl(3) solution and H(2)O(2) solution, respectively, and then the surface was modified with stearic acid (SA). The topological structure and surface wettability of the prepared mesh were characterized by fluorescence microscope, scanning electron microscopy and contact angle measurement. Finally, the as-prepared copper meshes were applied to oil-water separation. The results showed that the micro-nano-mastoid structure on the surface of the copper mesh was flaky bulges, forming a rough structure similar to a paraboloid. When the oxidative corrosion time of H(2)O(2) was 1 min, it is more beneficial to increase the hydrophobicity of the surface of the copper mesh and increase the contact angle of water droplets on the surface of the membrane. Additionally, based on superhydrophobic materials of the parabolic copper mesh, the static contact angles of the water droplets, engine oil and carbon tetrachloride with the surface were approximately 153.6°, 5° and 0.1°, respectively and the sliding angle of the water droplets with the surface were approximately 4.9°. The parabolic membrane was applied to discuss the separation efficiency of different oils with deionized water and the separation efficiency was obtained as benzene > carbon tetrachloride > oil > machine oil. Therefore, based on the research, the parabolic superhydrophobic material has good efficiency of oil-water separation. MDPI 2018-10-09 /pmc/articles/PMC6213289/ /pubmed/30304798 http://dx.doi.org/10.3390/ma11101914 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Qiao, Xiaoying Yang, Chunyan Zhang, Qian Yang, Shengke Chen, Yangyang Zhang, Dan Yuan, Xiaoyu Wang, Wenke Zhao, Yaqian Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation |
title | Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation |
title_full | Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation |
title_fullStr | Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation |
title_full_unstemmed | Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation |
title_short | Preparation of Parabolic Superhydrophobic Material for Oil-Water Separation |
title_sort | preparation of parabolic superhydrophobic material for oil-water separation |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6213289/ https://www.ncbi.nlm.nih.gov/pubmed/30304798 http://dx.doi.org/10.3390/ma11101914 |
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