Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black

A model of rubber with a cross-linked rubber layer on a carbon black filler has been proposed. The cross-links are the result of free radical reactions generated by carbon atoms with unpaired electrons at the edge of graphitic sheets in a carbon black filler. The experimental study of the cross-link...

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Autores principales: Kondyurin, Alexey V., Eliseeva, Anastasia Yu., Svistkov, Alexander L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6213853/
https://www.ncbi.nlm.nih.gov/pubmed/30332746
http://dx.doi.org/10.3390/ma11101992
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author Kondyurin, Alexey V.
Eliseeva, Anastasia Yu.
Svistkov, Alexander L.
author_facet Kondyurin, Alexey V.
Eliseeva, Anastasia Yu.
Svistkov, Alexander L.
author_sort Kondyurin, Alexey V.
collection PubMed
description A model of rubber with a cross-linked rubber layer on a carbon black filler has been proposed. The cross-links are the result of free radical reactions generated by carbon atoms with unpaired electrons at the edge of graphitic sheets in a carbon black filler. The experimental study of the cross-linking reactions in polyisoprene was done on a flat carbonized surface after ion beam implantation. The cross-linking process in the polyisoprene macromolecules between two particles was simulated. The model with a cross-linked rubber layer on a carbon filler as a “glassy layer” explains the mechanical properties of the rubber materials.
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spelling pubmed-62138532018-11-14 Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black Kondyurin, Alexey V. Eliseeva, Anastasia Yu. Svistkov, Alexander L. Materials (Basel) Article A model of rubber with a cross-linked rubber layer on a carbon black filler has been proposed. The cross-links are the result of free radical reactions generated by carbon atoms with unpaired electrons at the edge of graphitic sheets in a carbon black filler. The experimental study of the cross-linking reactions in polyisoprene was done on a flat carbonized surface after ion beam implantation. The cross-linking process in the polyisoprene macromolecules between two particles was simulated. The model with a cross-linked rubber layer on a carbon filler as a “glassy layer” explains the mechanical properties of the rubber materials. MDPI 2018-10-16 /pmc/articles/PMC6213853/ /pubmed/30332746 http://dx.doi.org/10.3390/ma11101992 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Kondyurin, Alexey V.
Eliseeva, Anastasia Yu.
Svistkov, Alexander L.
Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black
title Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black
title_full Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black
title_fullStr Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black
title_full_unstemmed Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black
title_short Bound (“Glassy”) Rubber as a Free Radical Cross-linked Rubber Layer on a Carbon Black
title_sort bound (“glassy”) rubber as a free radical cross-linked rubber layer on a carbon black
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6213853/
https://www.ncbi.nlm.nih.gov/pubmed/30332746
http://dx.doi.org/10.3390/ma11101992
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