Synthesis of O-1–O-6 Substituted Positional Isomers of d-Glucose–Thioether Ligands and Their Ruthenium Polypyridyl Conjugates

[Image: see text] A library of positional isomers of d-glucose (O-1–O-6) as ligands and their 11 light-active ruthenium conjugates has been synthesized. A protecting group strategy without the necessity of using palladium on carbon for the modification for the 2-O and 4-O position allows for the inc...

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Autores principales: Lameijer, Lucien N., le Roy, Julien, van der Vorm, Stefan, Bonnet, Sylvestre
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218880/
https://www.ncbi.nlm.nih.gov/pubmed/30272448
http://dx.doi.org/10.1021/acs.joc.8b01342
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author Lameijer, Lucien N.
le Roy, Julien
van der Vorm, Stefan
Bonnet, Sylvestre
author_facet Lameijer, Lucien N.
le Roy, Julien
van der Vorm, Stefan
Bonnet, Sylvestre
author_sort Lameijer, Lucien N.
collection PubMed
description [Image: see text] A library of positional isomers of d-glucose (O-1–O-6) as ligands and their 11 light-active ruthenium conjugates has been synthesized. A protecting group strategy without the necessity of using palladium on carbon for the modification for the 2-O and 4-O position allows for the incorporation of sulfur donor atoms as ligands for transition metal complexes.
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spelling pubmed-62188802018-11-07 Synthesis of O-1–O-6 Substituted Positional Isomers of d-Glucose–Thioether Ligands and Their Ruthenium Polypyridyl Conjugates Lameijer, Lucien N. le Roy, Julien van der Vorm, Stefan Bonnet, Sylvestre J Org Chem [Image: see text] A library of positional isomers of d-glucose (O-1–O-6) as ligands and their 11 light-active ruthenium conjugates has been synthesized. A protecting group strategy without the necessity of using palladium on carbon for the modification for the 2-O and 4-O position allows for the incorporation of sulfur donor atoms as ligands for transition metal complexes. American Chemical Society 2018-10-01 2018-11-02 /pmc/articles/PMC6218880/ /pubmed/30272448 http://dx.doi.org/10.1021/acs.joc.8b01342 Text en Copyright © 2018 American Chemical Society This is an open access article published under a Creative Commons Non-Commercial No Derivative Works (CC-BY-NC-ND) Attribution License (http://pubs.acs.org/page/policy/authorchoice_ccbyncnd_termsofuse.html) , which permits copying and redistribution of the article, and creation of adaptations, all for non-commercial purposes.
spellingShingle Lameijer, Lucien N.
le Roy, Julien
van der Vorm, Stefan
Bonnet, Sylvestre
Synthesis of O-1–O-6 Substituted Positional Isomers of d-Glucose–Thioether Ligands and Their Ruthenium Polypyridyl Conjugates
title Synthesis of O-1–O-6 Substituted Positional Isomers of d-Glucose–Thioether Ligands and Their Ruthenium Polypyridyl Conjugates
title_full Synthesis of O-1–O-6 Substituted Positional Isomers of d-Glucose–Thioether Ligands and Their Ruthenium Polypyridyl Conjugates
title_fullStr Synthesis of O-1–O-6 Substituted Positional Isomers of d-Glucose–Thioether Ligands and Their Ruthenium Polypyridyl Conjugates
title_full_unstemmed Synthesis of O-1–O-6 Substituted Positional Isomers of d-Glucose–Thioether Ligands and Their Ruthenium Polypyridyl Conjugates
title_short Synthesis of O-1–O-6 Substituted Positional Isomers of d-Glucose–Thioether Ligands and Their Ruthenium Polypyridyl Conjugates
title_sort synthesis of o-1–o-6 substituted positional isomers of d-glucose–thioether ligands and their ruthenium polypyridyl conjugates
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218880/
https://www.ncbi.nlm.nih.gov/pubmed/30272448
http://dx.doi.org/10.1021/acs.joc.8b01342
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