Crystal structure of bis­(diiso­propyl­ammonium) molybdate

The organic–inorganic title salt, (C(6)H(16)N)(2)[MoO(4)] or ((i)Pr(2)NH(2))(2)[MoO(4)], was obtained by reacting MoO(3) with diiso­propyl­amine in a 1:2 molar ratio in water. The molybdate anion is located on a twofold rotation axis and exhibits a slightly distorted tetra­hedral configuration. In t...

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Autores principales: Sarr, Bougar, Mbaye, Abdou, Diop, Cheikh Abdoul Khadir, Melin, Frederic, Hellwig, Petra, Sidibé, Mamadou, Rousselin, Yoann
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218890/
https://www.ncbi.nlm.nih.gov/pubmed/30443406
http://dx.doi.org/10.1107/S2056989018014755
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author Sarr, Bougar
Mbaye, Abdou
Diop, Cheikh Abdoul Khadir
Melin, Frederic
Hellwig, Petra
Sidibé, Mamadou
Rousselin, Yoann
author_facet Sarr, Bougar
Mbaye, Abdou
Diop, Cheikh Abdoul Khadir
Melin, Frederic
Hellwig, Petra
Sidibé, Mamadou
Rousselin, Yoann
author_sort Sarr, Bougar
collection PubMed
description The organic–inorganic title salt, (C(6)H(16)N)(2)[MoO(4)] or ((i)Pr(2)NH(2))(2)[MoO(4)], was obtained by reacting MoO(3) with diiso­propyl­amine in a 1:2 molar ratio in water. The molybdate anion is located on a twofold rotation axis and exhibits a slightly distorted tetra­hedral configuration. In the crystal structure, the diiso­propyl­ammmonium ((i)Pr(2)NH(2))(+) cations and [MoO(4)](2−) anions are linked to each other through N—H⋯O hydrogen bonds, generating rings with R (12) (12)(36) motifs that give rise to the formation of a three-dimensional network. The structure was refined taking into account inversion twinning (ratio of ca 4:1 between the two domains).
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spelling pubmed-62188902018-11-15 Crystal structure of bis­(diiso­propyl­ammonium) molybdate Sarr, Bougar Mbaye, Abdou Diop, Cheikh Abdoul Khadir Melin, Frederic Hellwig, Petra Sidibé, Mamadou Rousselin, Yoann Acta Crystallogr E Crystallogr Commun Research Communications The organic–inorganic title salt, (C(6)H(16)N)(2)[MoO(4)] or ((i)Pr(2)NH(2))(2)[MoO(4)], was obtained by reacting MoO(3) with diiso­propyl­amine in a 1:2 molar ratio in water. The molybdate anion is located on a twofold rotation axis and exhibits a slightly distorted tetra­hedral configuration. In the crystal structure, the diiso­propyl­ammmonium ((i)Pr(2)NH(2))(+) cations and [MoO(4)](2−) anions are linked to each other through N—H⋯O hydrogen bonds, generating rings with R (12) (12)(36) motifs that give rise to the formation of a three-dimensional network. The structure was refined taking into account inversion twinning (ratio of ca 4:1 between the two domains). International Union of Crystallography 2018-10-31 /pmc/articles/PMC6218890/ /pubmed/30443406 http://dx.doi.org/10.1107/S2056989018014755 Text en © Sarr et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Sarr, Bougar
Mbaye, Abdou
Diop, Cheikh Abdoul Khadir
Melin, Frederic
Hellwig, Petra
Sidibé, Mamadou
Rousselin, Yoann
Crystal structure of bis­(diiso­propyl­ammonium) molybdate
title Crystal structure of bis­(diiso­propyl­ammonium) molybdate
title_full Crystal structure of bis­(diiso­propyl­ammonium) molybdate
title_fullStr Crystal structure of bis­(diiso­propyl­ammonium) molybdate
title_full_unstemmed Crystal structure of bis­(diiso­propyl­ammonium) molybdate
title_short Crystal structure of bis­(diiso­propyl­ammonium) molybdate
title_sort crystal structure of bis­(diiso­propyl­ammonium) molybdate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218890/
https://www.ncbi.nlm.nih.gov/pubmed/30443406
http://dx.doi.org/10.1107/S2056989018014755
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