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Crystal structure of N-isopropyl-N-(phenyl)phenylglyoxylamide
The title compound [systematic name: 2-oxo-N,2-diphenyl-N-(propan-2-yl)acetamide], C(17)H(17)NO(2), was synthesized and its photoreactive properties in the crystalline state were investigated. In the molecule, the carbonyl group attached to the phenyl ring adopts an s-trans configuration with respe...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218892/ https://www.ncbi.nlm.nih.gov/pubmed/30443383 http://dx.doi.org/10.1107/S2056989018013762 |
Sumario: | The title compound [systematic name: 2-oxo-N,2-diphenyl-N-(propan-2-yl)acetamide], C(17)H(17)NO(2), was synthesized and its photoreactive properties in the crystalline state were investigated. In the molecule, the carbonyl group attached to the phenyl ring adopts an s-trans configuration with respect to the isopropyl group. Moreover, the distance between the C atom of the carbonyl group and the N-bound C atom of the isopropyl group is 3.845 (2) Å, which is much longer than 3.2 Å, the threshold for photoreactions to take place in the molecule. As a result, the crystal did not photoreact upon UV light irradiation. In the crystal, the molecules are linked via weak intermolecular C—H⋯O hydrogen bonds, forming a layer structure parallel to the ab plane. |
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