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Crystal structure of N-isopropyl-N-(phen­yl)phenyl­glyoxyl­amide

The title compound [systematic name: 2-oxo-N,2-diphenyl-N-(propan-2-yl)acetamide], C(17)H(17)NO(2), was synthesized and its photoreactive properties in the crystalline state were investigated. In the mol­ecule, the carbonyl group attached to the phenyl ring adopts an s-trans configuration with respe...

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Detalles Bibliográficos
Autores principales: Miyamoto, Hisakazu, Yamauchi, Genta, Ueno, Takuya, Uekusa, Hidehiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218892/
https://www.ncbi.nlm.nih.gov/pubmed/30443383
http://dx.doi.org/10.1107/S2056989018013762
Descripción
Sumario:The title compound [systematic name: 2-oxo-N,2-diphenyl-N-(propan-2-yl)acetamide], C(17)H(17)NO(2), was synthesized and its photoreactive properties in the crystalline state were investigated. In the mol­ecule, the carbonyl group attached to the phenyl ring adopts an s-trans configuration with respect to the isopropyl group. Moreover, the distance between the C atom of the carbonyl group and the N-bound C atom of the isopropyl group is 3.845 (2) Å, which is much longer than 3.2 Å, the threshold for photoreactions to take place in the mol­ecule. As a result, the crystal did not photoreact upon UV light irradiation. In the crystal, the mol­ecules are linked via weak inter­molecular C—H⋯O hydrogen bonds, forming a layer structure parallel to the ab plane.