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Crystal structure of N-isopropyl-N-(phen­yl)phenyl­glyoxyl­amide

The title compound [systematic name: 2-oxo-N,2-diphenyl-N-(propan-2-yl)acetamide], C(17)H(17)NO(2), was synthesized and its photoreactive properties in the crystalline state were investigated. In the mol­ecule, the carbonyl group attached to the phenyl ring adopts an s-trans configuration with respe...

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Autores principales: Miyamoto, Hisakazu, Yamauchi, Genta, Ueno, Takuya, Uekusa, Hidehiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218892/
https://www.ncbi.nlm.nih.gov/pubmed/30443383
http://dx.doi.org/10.1107/S2056989018013762
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author Miyamoto, Hisakazu
Yamauchi, Genta
Ueno, Takuya
Uekusa, Hidehiro
author_facet Miyamoto, Hisakazu
Yamauchi, Genta
Ueno, Takuya
Uekusa, Hidehiro
author_sort Miyamoto, Hisakazu
collection PubMed
description The title compound [systematic name: 2-oxo-N,2-diphenyl-N-(propan-2-yl)acetamide], C(17)H(17)NO(2), was synthesized and its photoreactive properties in the crystalline state were investigated. In the mol­ecule, the carbonyl group attached to the phenyl ring adopts an s-trans configuration with respect to the isopropyl group. Moreover, the distance between the C atom of the carbonyl group and the N-bound C atom of the isopropyl group is 3.845 (2) Å, which is much longer than 3.2 Å, the threshold for photoreactions to take place in the mol­ecule. As a result, the crystal did not photoreact upon UV light irradiation. In the crystal, the mol­ecules are linked via weak inter­molecular C—H⋯O hydrogen bonds, forming a layer structure parallel to the ab plane.
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spelling pubmed-62188922018-11-15 Crystal structure of N-isopropyl-N-(phen­yl)phenyl­glyoxyl­amide Miyamoto, Hisakazu Yamauchi, Genta Ueno, Takuya Uekusa, Hidehiro Acta Crystallogr E Crystallogr Commun Research Communications The title compound [systematic name: 2-oxo-N,2-diphenyl-N-(propan-2-yl)acetamide], C(17)H(17)NO(2), was synthesized and its photoreactive properties in the crystalline state were investigated. In the mol­ecule, the carbonyl group attached to the phenyl ring adopts an s-trans configuration with respect to the isopropyl group. Moreover, the distance between the C atom of the carbonyl group and the N-bound C atom of the isopropyl group is 3.845 (2) Å, which is much longer than 3.2 Å, the threshold for photoreactions to take place in the mol­ecule. As a result, the crystal did not photoreact upon UV light irradiation. In the crystal, the mol­ecules are linked via weak inter­molecular C—H⋯O hydrogen bonds, forming a layer structure parallel to the ab plane. International Union of Crystallography 2018-10-12 /pmc/articles/PMC6218892/ /pubmed/30443383 http://dx.doi.org/10.1107/S2056989018013762 Text en © Miyamoto et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Miyamoto, Hisakazu
Yamauchi, Genta
Ueno, Takuya
Uekusa, Hidehiro
Crystal structure of N-isopropyl-N-(phen­yl)phenyl­glyoxyl­amide
title Crystal structure of N-isopropyl-N-(phen­yl)phenyl­glyoxyl­amide
title_full Crystal structure of N-isopropyl-N-(phen­yl)phenyl­glyoxyl­amide
title_fullStr Crystal structure of N-isopropyl-N-(phen­yl)phenyl­glyoxyl­amide
title_full_unstemmed Crystal structure of N-isopropyl-N-(phen­yl)phenyl­glyoxyl­amide
title_short Crystal structure of N-isopropyl-N-(phen­yl)phenyl­glyoxyl­amide
title_sort crystal structure of n-isopropyl-n-(phen­yl)phenyl­glyoxyl­amide
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218892/
https://www.ncbi.nlm.nih.gov/pubmed/30443383
http://dx.doi.org/10.1107/S2056989018013762
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