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Crystal structure of N-isopropyl-N-(phenyl)phenylglyoxylamide
The title compound [systematic name: 2-oxo-N,2-diphenyl-N-(propan-2-yl)acetamide], C(17)H(17)NO(2), was synthesized and its photoreactive properties in the crystalline state were investigated. In the molecule, the carbonyl group attached to the phenyl ring adopts an s-trans configuration with respe...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218892/ https://www.ncbi.nlm.nih.gov/pubmed/30443383 http://dx.doi.org/10.1107/S2056989018013762 |
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author | Miyamoto, Hisakazu Yamauchi, Genta Ueno, Takuya Uekusa, Hidehiro |
author_facet | Miyamoto, Hisakazu Yamauchi, Genta Ueno, Takuya Uekusa, Hidehiro |
author_sort | Miyamoto, Hisakazu |
collection | PubMed |
description | The title compound [systematic name: 2-oxo-N,2-diphenyl-N-(propan-2-yl)acetamide], C(17)H(17)NO(2), was synthesized and its photoreactive properties in the crystalline state were investigated. In the molecule, the carbonyl group attached to the phenyl ring adopts an s-trans configuration with respect to the isopropyl group. Moreover, the distance between the C atom of the carbonyl group and the N-bound C atom of the isopropyl group is 3.845 (2) Å, which is much longer than 3.2 Å, the threshold for photoreactions to take place in the molecule. As a result, the crystal did not photoreact upon UV light irradiation. In the crystal, the molecules are linked via weak intermolecular C—H⋯O hydrogen bonds, forming a layer structure parallel to the ab plane. |
format | Online Article Text |
id | pubmed-6218892 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2018 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-62188922018-11-15 Crystal structure of N-isopropyl-N-(phenyl)phenylglyoxylamide Miyamoto, Hisakazu Yamauchi, Genta Ueno, Takuya Uekusa, Hidehiro Acta Crystallogr E Crystallogr Commun Research Communications The title compound [systematic name: 2-oxo-N,2-diphenyl-N-(propan-2-yl)acetamide], C(17)H(17)NO(2), was synthesized and its photoreactive properties in the crystalline state were investigated. In the molecule, the carbonyl group attached to the phenyl ring adopts an s-trans configuration with respect to the isopropyl group. Moreover, the distance between the C atom of the carbonyl group and the N-bound C atom of the isopropyl group is 3.845 (2) Å, which is much longer than 3.2 Å, the threshold for photoreactions to take place in the molecule. As a result, the crystal did not photoreact upon UV light irradiation. In the crystal, the molecules are linked via weak intermolecular C—H⋯O hydrogen bonds, forming a layer structure parallel to the ab plane. International Union of Crystallography 2018-10-12 /pmc/articles/PMC6218892/ /pubmed/30443383 http://dx.doi.org/10.1107/S2056989018013762 Text en © Miyamoto et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/ |
spellingShingle | Research Communications Miyamoto, Hisakazu Yamauchi, Genta Ueno, Takuya Uekusa, Hidehiro Crystal structure of N-isopropyl-N-(phenyl)phenylglyoxylamide |
title | Crystal structure of N-isopropyl-N-(phenyl)phenylglyoxylamide |
title_full | Crystal structure of N-isopropyl-N-(phenyl)phenylglyoxylamide |
title_fullStr | Crystal structure of N-isopropyl-N-(phenyl)phenylglyoxylamide |
title_full_unstemmed | Crystal structure of N-isopropyl-N-(phenyl)phenylglyoxylamide |
title_short | Crystal structure of N-isopropyl-N-(phenyl)phenylglyoxylamide |
title_sort | crystal structure of n-isopropyl-n-(phenyl)phenylglyoxylamide |
topic | Research Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218892/ https://www.ncbi.nlm.nih.gov/pubmed/30443383 http://dx.doi.org/10.1107/S2056989018013762 |
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