Crystal structure of 5,15-dihexyl-5,15-di­hydro­benzo[2,1-b:4,3-c′]dicarbazole hexane 0.375-solvate

The title compound, C(38)H(40)N(2)·0.375C(6)H(14), crystallizes in the monoclinic space group P2(1)/c and has a host–guest structure with the helicene molecules forming a porous structure and mol­ecules of hexane inserted into the holes. The dihedral angles between the two carbazole sections of the...

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Autores principales: Zhang, Dingchao, Shi, Longqiang, Liu, Zhi, Li, Li, Hu, Zhenhao, Cui, Deliang, Yang, Jing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218895/
https://www.ncbi.nlm.nih.gov/pubmed/30443390
http://dx.doi.org/10.1107/S2056989018014512
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author Zhang, Dingchao
Shi, Longqiang
Liu, Zhi
Li, Li
Hu, Zhenhao
Cui, Deliang
Yang, Jing
author_facet Zhang, Dingchao
Shi, Longqiang
Liu, Zhi
Li, Li
Hu, Zhenhao
Cui, Deliang
Yang, Jing
author_sort Zhang, Dingchao
collection PubMed
description The title compound, C(38)H(40)N(2)·0.375C(6)H(14), crystallizes in the monoclinic space group P2(1)/c and has a host–guest structure with the helicene molecules forming a porous structure and mol­ecules of hexane inserted into the holes. The dihedral angles between the two carbazole sections of the right- and left-handed helicenes are 27.44 (3) and 25.63 (3)°, respectively. There are no classical π–π inter­actions or hydrogen-bonding inter­actions present between adjacent mol­ecules in the crystal structure. The hexane solvent mol­ecule shows positional disorder.
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spelling pubmed-62188952018-11-15 Crystal structure of 5,15-dihexyl-5,15-di­hydro­benzo[2,1-b:4,3-c′]dicarbazole hexane 0.375-solvate Zhang, Dingchao Shi, Longqiang Liu, Zhi Li, Li Hu, Zhenhao Cui, Deliang Yang, Jing Acta Crystallogr E Crystallogr Commun Research Communications The title compound, C(38)H(40)N(2)·0.375C(6)H(14), crystallizes in the monoclinic space group P2(1)/c and has a host–guest structure with the helicene molecules forming a porous structure and mol­ecules of hexane inserted into the holes. The dihedral angles between the two carbazole sections of the right- and left-handed helicenes are 27.44 (3) and 25.63 (3)°, respectively. There are no classical π–π inter­actions or hydrogen-bonding inter­actions present between adjacent mol­ecules in the crystal structure. The hexane solvent mol­ecule shows positional disorder. International Union of Crystallography 2018-10-19 /pmc/articles/PMC6218895/ /pubmed/30443390 http://dx.doi.org/10.1107/S2056989018014512 Text en © Zhang et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Zhang, Dingchao
Shi, Longqiang
Liu, Zhi
Li, Li
Hu, Zhenhao
Cui, Deliang
Yang, Jing
Crystal structure of 5,15-dihexyl-5,15-di­hydro­benzo[2,1-b:4,3-c′]dicarbazole hexane 0.375-solvate
title Crystal structure of 5,15-dihexyl-5,15-di­hydro­benzo[2,1-b:4,3-c′]dicarbazole hexane 0.375-solvate
title_full Crystal structure of 5,15-dihexyl-5,15-di­hydro­benzo[2,1-b:4,3-c′]dicarbazole hexane 0.375-solvate
title_fullStr Crystal structure of 5,15-dihexyl-5,15-di­hydro­benzo[2,1-b:4,3-c′]dicarbazole hexane 0.375-solvate
title_full_unstemmed Crystal structure of 5,15-dihexyl-5,15-di­hydro­benzo[2,1-b:4,3-c′]dicarbazole hexane 0.375-solvate
title_short Crystal structure of 5,15-dihexyl-5,15-di­hydro­benzo[2,1-b:4,3-c′]dicarbazole hexane 0.375-solvate
title_sort crystal structure of 5,15-dihexyl-5,15-di­hydro­benzo[2,1-b:4,3-c′]dicarbazole hexane 0.375-solvate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218895/
https://www.ncbi.nlm.nih.gov/pubmed/30443390
http://dx.doi.org/10.1107/S2056989018014512
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