Crystal structure and Hirshfeld surface analysis of (E)-1-[(4,7-di­methyl­quinolin-2-yl)methyl­idene]semicarbazide dihydrate

In the title compound, C(13)H(14)N(4)O·2H(2)O, the organic mol­ecule is almost planar. In the crystal, the mol­ecules are linked by O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds, forming a two-dimensional network parallel to (10[Image: see text]). Hirshfeld surface analysis and two-dimensional fingerprint p...

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Autores principales: Aydemir, Ercan, Kansiz, Sevgi, Dege, Necmi, Genc, Hasan, Gaidai, Snizhana V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218908/
https://www.ncbi.nlm.nih.gov/pubmed/30443404
http://dx.doi.org/10.1107/S2056989018014925
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author Aydemir, Ercan
Kansiz, Sevgi
Dege, Necmi
Genc, Hasan
Gaidai, Snizhana V.
author_facet Aydemir, Ercan
Kansiz, Sevgi
Dege, Necmi
Genc, Hasan
Gaidai, Snizhana V.
author_sort Aydemir, Ercan
collection PubMed
description In the title compound, C(13)H(14)N(4)O·2H(2)O, the organic mol­ecule is almost planar. In the crystal, the mol­ecules are linked by O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds, forming a two-dimensional network parallel to (10[Image: see text]). Hirshfeld surface analysis and two-dimensional fingerprint plots indicate that the most important contributions to the crystal packing are from H⋯H (55.4%), H⋯O/O⋯H (14.8%), H⋯C/C⋯H (11.7%) and H⋯N/N⋯H (8.3%) inter­actions.
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spelling pubmed-62189082018-11-15 Crystal structure and Hirshfeld surface analysis of (E)-1-[(4,7-di­methyl­quinolin-2-yl)methyl­idene]semicarbazide dihydrate Aydemir, Ercan Kansiz, Sevgi Dege, Necmi Genc, Hasan Gaidai, Snizhana V. Acta Crystallogr E Crystallogr Commun Research Communications In the title compound, C(13)H(14)N(4)O·2H(2)O, the organic mol­ecule is almost planar. In the crystal, the mol­ecules are linked by O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds, forming a two-dimensional network parallel to (10[Image: see text]). Hirshfeld surface analysis and two-dimensional fingerprint plots indicate that the most important contributions to the crystal packing are from H⋯H (55.4%), H⋯O/O⋯H (14.8%), H⋯C/C⋯H (11.7%) and H⋯N/N⋯H (8.3%) inter­actions. International Union of Crystallography 2018-10-31 /pmc/articles/PMC6218908/ /pubmed/30443404 http://dx.doi.org/10.1107/S2056989018014925 Text en © Aydemir et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Aydemir, Ercan
Kansiz, Sevgi
Dege, Necmi
Genc, Hasan
Gaidai, Snizhana V.
Crystal structure and Hirshfeld surface analysis of (E)-1-[(4,7-di­methyl­quinolin-2-yl)methyl­idene]semicarbazide dihydrate
title Crystal structure and Hirshfeld surface analysis of (E)-1-[(4,7-di­methyl­quinolin-2-yl)methyl­idene]semicarbazide dihydrate
title_full Crystal structure and Hirshfeld surface analysis of (E)-1-[(4,7-di­methyl­quinolin-2-yl)methyl­idene]semicarbazide dihydrate
title_fullStr Crystal structure and Hirshfeld surface analysis of (E)-1-[(4,7-di­methyl­quinolin-2-yl)methyl­idene]semicarbazide dihydrate
title_full_unstemmed Crystal structure and Hirshfeld surface analysis of (E)-1-[(4,7-di­methyl­quinolin-2-yl)methyl­idene]semicarbazide dihydrate
title_short Crystal structure and Hirshfeld surface analysis of (E)-1-[(4,7-di­methyl­quinolin-2-yl)methyl­idene]semicarbazide dihydrate
title_sort crystal structure and hirshfeld surface analysis of (e)-1-[(4,7-di­methyl­quinolin-2-yl)methyl­idene]semicarbazide dihydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218908/
https://www.ncbi.nlm.nih.gov/pubmed/30443404
http://dx.doi.org/10.1107/S2056989018014925
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