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Crystal structure and Hirshfeld surface analysis of (Z)-4-chloro-N′-(4-oxothiazolidin-2-ylidene)benzenesulfonohydrazide monohydrate
The asymmetric unit of the title thiazole derivative containing a sulfonylhydrazinic moiety, C(9)H(8)ClN(3)O(3)S(2)·H(2)O, consists of two independent molecules and two water molecules. The central parts of the molecules are twisted as both the molecules are bent at both the S and N atoms. In...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218911/ https://www.ncbi.nlm.nih.gov/pubmed/30443382 http://dx.doi.org/10.1107/S2056989018013658 |
Sumario: | The asymmetric unit of the title thiazole derivative containing a sulfonylhydrazinic moiety, C(9)H(8)ClN(3)O(3)S(2)·H(2)O, consists of two independent molecules and two water molecules. The central parts of the molecules are twisted as both the molecules are bent at both the S and N atoms. In the crystal, N—H⋯N, N—H⋯O, C—H⋯O and O—H⋯O hydrogen-bonding interactions connect the molecules, forming layers parallel to the ab plane. Two-dimensional fingerprint plots associated with the Hirshfeld surface show that the largest contributions to the crystal packing come from O⋯H/H⋯O (32.9%) and H⋯H (22.6%) interactions. |
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