Cargando…

Crystal structure of di­chlorido­bis­{μ-2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}{2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}cadmium(II)cobalt(III) monohydrate

The title compound, [CoCd(C(9)H(10)NO(2))(3)Cl(2)]·H(2)O, is a solvatomorph of the corresponding hemihydrate recently published by us [Nesterova et al. (2018 ▸). Appl. Cat. A, 560, 171–184]. The current structure reveals different cell parameters and space group compared with the published one while...

Descripción completa

Detalles Bibliográficos
Autores principales: Vassilyeva, Olga Yu., Kasyanova, Katerina V., Kokozay, Vladimir N., Skelton, Brian W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218914/
https://www.ncbi.nlm.nih.gov/pubmed/30443374
http://dx.doi.org/10.1107/S2056989018013610
_version_ 1783368546760261632
author Vassilyeva, Olga Yu.
Kasyanova, Katerina V.
Kokozay, Vladimir N.
Skelton, Brian W.
author_facet Vassilyeva, Olga Yu.
Kasyanova, Katerina V.
Kokozay, Vladimir N.
Skelton, Brian W.
author_sort Vassilyeva, Olga Yu.
collection PubMed
description The title compound, [CoCd(C(9)H(10)NO(2))(3)Cl(2)]·H(2)O, is a solvatomorph of the corresponding hemihydrate recently published by us [Nesterova et al. (2018 ▸). Appl. Cat. A, 560, 171–184]. The current structure reveals different cell parameters and space group compared with the published one while both are monoclinic with almost the same cell volume. The title compound is formed of discrete neutral dinuclear mol­ecules with no crystallographically imposed symmetry and water mol­ecules of crystallization. The overall geometry about the cobalt(III) ion is octa­hedral with an N(3)O(3) environment; each ligand acts as a meridional ONO donor. The Cd(II) coordination sphere approximates an irregular square pyramid with a chlorine atom at the apex. There is significant shortening of a Cd—O bond length to the oxygen atom of the methoxo group on one of the ligands [2.459 (3) Å] compared to the corresponding distance in the published structure [2.724 (7) Å], while other Cd—Cl/N/O bonds remain roughly the same. In the crystal lattice, the heterometallic mol­ecules, which are related by the crystallographic n-glide plane and inter­linked by weak hydrogen bonds to solvent water mol­ecules, form columns along [101]. Adjacent columns lie anti­parallel to each other.
format Online
Article
Text
id pubmed-6218914
institution National Center for Biotechnology Information
language English
publishDate 2018
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-62189142018-11-15 Crystal structure of di­chlorido­bis­{μ-2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}{2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}cadmium(II)cobalt(III) monohydrate Vassilyeva, Olga Yu. Kasyanova, Katerina V. Kokozay, Vladimir N. Skelton, Brian W. Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [CoCd(C(9)H(10)NO(2))(3)Cl(2)]·H(2)O, is a solvatomorph of the corresponding hemihydrate recently published by us [Nesterova et al. (2018 ▸). Appl. Cat. A, 560, 171–184]. The current structure reveals different cell parameters and space group compared with the published one while both are monoclinic with almost the same cell volume. The title compound is formed of discrete neutral dinuclear mol­ecules with no crystallographically imposed symmetry and water mol­ecules of crystallization. The overall geometry about the cobalt(III) ion is octa­hedral with an N(3)O(3) environment; each ligand acts as a meridional ONO donor. The Cd(II) coordination sphere approximates an irregular square pyramid with a chlorine atom at the apex. There is significant shortening of a Cd—O bond length to the oxygen atom of the methoxo group on one of the ligands [2.459 (3) Å] compared to the corresponding distance in the published structure [2.724 (7) Å], while other Cd—Cl/N/O bonds remain roughly the same. In the crystal lattice, the heterometallic mol­ecules, which are related by the crystallographic n-glide plane and inter­linked by weak hydrogen bonds to solvent water mol­ecules, form columns along [101]. Adjacent columns lie anti­parallel to each other. International Union of Crystallography 2018-10-02 /pmc/articles/PMC6218914/ /pubmed/30443374 http://dx.doi.org/10.1107/S2056989018013610 Text en © Vassilyeva et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Vassilyeva, Olga Yu.
Kasyanova, Katerina V.
Kokozay, Vladimir N.
Skelton, Brian W.
Crystal structure of di­chlorido­bis­{μ-2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}{2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}cadmium(II)cobalt(III) monohydrate
title Crystal structure of di­chlorido­bis­{μ-2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}{2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}cadmium(II)cobalt(III) monohydrate
title_full Crystal structure of di­chlorido­bis­{μ-2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}{2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}cadmium(II)cobalt(III) monohydrate
title_fullStr Crystal structure of di­chlorido­bis­{μ-2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}{2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}cadmium(II)cobalt(III) monohydrate
title_full_unstemmed Crystal structure of di­chlorido­bis­{μ-2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}{2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}cadmium(II)cobalt(III) monohydrate
title_short Crystal structure of di­chlorido­bis­{μ-2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}{2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}cadmium(II)cobalt(III) monohydrate
title_sort crystal structure of di­chlorido­bis­{μ-2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}{2-meth­oxy-6-[(methyl­imino)­meth­yl]phenolato}cadmium(ii)cobalt(iii) monohydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218914/
https://www.ncbi.nlm.nih.gov/pubmed/30443374
http://dx.doi.org/10.1107/S2056989018013610
work_keys_str_mv AT vassilyevaolgayu crystalstructureofdichloridobism2methoxy6methyliminomethylphenolato2methoxy6methyliminomethylphenolatocadmiumiicobaltiiimonohydrate
AT kasyanovakaterinav crystalstructureofdichloridobism2methoxy6methyliminomethylphenolato2methoxy6methyliminomethylphenolatocadmiumiicobaltiiimonohydrate
AT kokozayvladimirn crystalstructureofdichloridobism2methoxy6methyliminomethylphenolato2methoxy6methyliminomethylphenolatocadmiumiicobaltiiimonohydrate
AT skeltonbrianw crystalstructureofdichloridobism2methoxy6methyliminomethylphenolato2methoxy6methyliminomethylphenolatocadmiumiicobaltiiimonohydrate