Crystal structure at 100 K of bis­[1,2-bis­(di­phenyl­phosphan­yl)ethane]­nickel(II) bis­(tri­fluoro­methane­sulfonate): a possible negative thermal expansion mol­ecular material

In the title salt, [Ni(C(26)H(24)P(2))(2)](CF(3)SO(3))(2) or [Ni(dppe)(2)](2+)·(OTf(−))(2) [dppe = 1,2-bis­(di­phenyl­phosphan­yl)ethane and OTf(−) = tri­fluoro­methane­sulfonate], the Ni atom (site symmetry [Image: see text]) has a square-planar geometry with the bidentate ligands chelating the met...

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Detalles Bibliográficos
Autores principales: Cano-Benítez, Cristian A., Metta-Magaña, Alejandro J., Duarte-Ruiz, Álvaro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218916/
https://www.ncbi.nlm.nih.gov/pubmed/30443405
http://dx.doi.org/10.1107/S2056989018014846

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