Crystal structure and thermal properties of bis­[μ-2-(meth­oxy­carbonyl­hydrazinyl­idene)acetato-κ(3) N (1),O:O]bis­[di­aqua­(thio­cyanato-κN)manganese(II)] tetra­hydrate

The title compound, [Mn(2)(C(4)H(5)N(2)O(4))(2)(NCS)(2)(H(2)O)(4)]·4H(2)O (I), exists as a centrosymmetric dimer. Each dimeric unit consists of tridentate (O,O,N)-chelating Schiff bases with symmetry-maintained μ-O-bridged carboxyl­ate anions, terminally bound thio­cyanate anions, and ligated and so...

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Autores principales: Poornima, Subbiyan, Premkumar, Thathan, Butcher, Raymond J., Govindarajan, Subbaiah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218922/
https://www.ncbi.nlm.nih.gov/pubmed/30443400
http://dx.doi.org/10.1107/S2056989018014871
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author Poornima, Subbiyan
Premkumar, Thathan
Butcher, Raymond J.
Govindarajan, Subbaiah
author_facet Poornima, Subbiyan
Premkumar, Thathan
Butcher, Raymond J.
Govindarajan, Subbaiah
author_sort Poornima, Subbiyan
collection PubMed
description The title compound, [Mn(2)(C(4)H(5)N(2)O(4))(2)(NCS)(2)(H(2)O)(4)]·4H(2)O (I), exists as a centrosymmetric dimer. Each dimeric unit consists of tridentate (O,O,N)-chelating Schiff bases with symmetry-maintained μ-O-bridged carboxyl­ate anions, terminally bound thio­cyanate anions, and ligated and solvated water mol­ecules. The complex exhibits a distorted octa­hedron geometry and the centrosymmetric μ-O-bridged carboxyl­ate anions connect the two manganese atoms to form an M (2)O(2) ring. In the crystal, the mol­ecules are inter­linked via strong N—H⋯O and O—H⋯O hydrogen-bonding contacts and weak O—H⋯S inter­molecular inter­actions, forming a three-dimensional mol­ecular network.
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spelling pubmed-62189222018-11-15 Crystal structure and thermal properties of bis­[μ-2-(meth­oxy­carbonyl­hydrazinyl­idene)acetato-κ(3) N (1),O:O]bis­[di­aqua­(thio­cyanato-κN)manganese(II)] tetra­hydrate Poornima, Subbiyan Premkumar, Thathan Butcher, Raymond J. Govindarajan, Subbaiah Acta Crystallogr E Crystallogr Commun Research Communications The title compound, [Mn(2)(C(4)H(5)N(2)O(4))(2)(NCS)(2)(H(2)O)(4)]·4H(2)O (I), exists as a centrosymmetric dimer. Each dimeric unit consists of tridentate (O,O,N)-chelating Schiff bases with symmetry-maintained μ-O-bridged carboxyl­ate anions, terminally bound thio­cyanate anions, and ligated and solvated water mol­ecules. The complex exhibits a distorted octa­hedron geometry and the centrosymmetric μ-O-bridged carboxyl­ate anions connect the two manganese atoms to form an M (2)O(2) ring. In the crystal, the mol­ecules are inter­linked via strong N—H⋯O and O—H⋯O hydrogen-bonding contacts and weak O—H⋯S inter­molecular inter­actions, forming a three-dimensional mol­ecular network. International Union of Crystallography 2018-10-26 /pmc/articles/PMC6218922/ /pubmed/30443400 http://dx.doi.org/10.1107/S2056989018014871 Text en © Poornima et al. 2018 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.http://creativecommons.org/licenses/by/2.0/uk/
spellingShingle Research Communications
Poornima, Subbiyan
Premkumar, Thathan
Butcher, Raymond J.
Govindarajan, Subbaiah
Crystal structure and thermal properties of bis­[μ-2-(meth­oxy­carbonyl­hydrazinyl­idene)acetato-κ(3) N (1),O:O]bis­[di­aqua­(thio­cyanato-κN)manganese(II)] tetra­hydrate
title Crystal structure and thermal properties of bis­[μ-2-(meth­oxy­carbonyl­hydrazinyl­idene)acetato-κ(3) N (1),O:O]bis­[di­aqua­(thio­cyanato-κN)manganese(II)] tetra­hydrate
title_full Crystal structure and thermal properties of bis­[μ-2-(meth­oxy­carbonyl­hydrazinyl­idene)acetato-κ(3) N (1),O:O]bis­[di­aqua­(thio­cyanato-κN)manganese(II)] tetra­hydrate
title_fullStr Crystal structure and thermal properties of bis­[μ-2-(meth­oxy­carbonyl­hydrazinyl­idene)acetato-κ(3) N (1),O:O]bis­[di­aqua­(thio­cyanato-κN)manganese(II)] tetra­hydrate
title_full_unstemmed Crystal structure and thermal properties of bis­[μ-2-(meth­oxy­carbonyl­hydrazinyl­idene)acetato-κ(3) N (1),O:O]bis­[di­aqua­(thio­cyanato-κN)manganese(II)] tetra­hydrate
title_short Crystal structure and thermal properties of bis­[μ-2-(meth­oxy­carbonyl­hydrazinyl­idene)acetato-κ(3) N (1),O:O]bis­[di­aqua­(thio­cyanato-κN)manganese(II)] tetra­hydrate
title_sort crystal structure and thermal properties of bis­[μ-2-(meth­oxy­carbonyl­hydrazinyl­idene)acetato-κ(3) n (1),o:o]bis­[di­aqua­(thio­cyanato-κn)manganese(ii)] tetra­hydrate
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6218922/
https://www.ncbi.nlm.nih.gov/pubmed/30443400
http://dx.doi.org/10.1107/S2056989018014871
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