Zirconium‐Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming

C‐saturated Pd(0) nanoparticles with an extended phase boundary to ZrO(2) evolve from a Pd(0)Zr(0) precatalyst under CH(4) dry reforming conditions. This highly active catalyst state fosters bifunctional action: CO(2) is efficiently activated at oxidic phase boundary sites and Pd(x)C provides fast s...

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Autores principales: Köpfle, Norbert, Götsch, Thomas, Grünbacher, Matthias, Carbonio, Emilia A., Hävecker, Michael, Knop‐Gericke, Axel, Schlicker, Lukas, Doran, Andrew, Kober, Delf, Gurlo, Aleksander, Penner, Simon, Klötzer, Bernhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6221108/
https://www.ncbi.nlm.nih.gov/pubmed/30179293
http://dx.doi.org/10.1002/anie.201807463
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author Köpfle, Norbert
Götsch, Thomas
Grünbacher, Matthias
Carbonio, Emilia A.
Hävecker, Michael
Knop‐Gericke, Axel
Schlicker, Lukas
Doran, Andrew
Kober, Delf
Gurlo, Aleksander
Penner, Simon
Klötzer, Bernhard
author_facet Köpfle, Norbert
Götsch, Thomas
Grünbacher, Matthias
Carbonio, Emilia A.
Hävecker, Michael
Knop‐Gericke, Axel
Schlicker, Lukas
Doran, Andrew
Kober, Delf
Gurlo, Aleksander
Penner, Simon
Klötzer, Bernhard
author_sort Köpfle, Norbert
collection PubMed
description C‐saturated Pd(0) nanoparticles with an extended phase boundary to ZrO(2) evolve from a Pd(0)Zr(0) precatalyst under CH(4) dry reforming conditions. This highly active catalyst state fosters bifunctional action: CO(2) is efficiently activated at oxidic phase boundary sites and Pd(x)C provides fast supply of C‐atoms toward the latter.
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spelling pubmed-62211082018-11-15 Zirconium‐Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming Köpfle, Norbert Götsch, Thomas Grünbacher, Matthias Carbonio, Emilia A. Hävecker, Michael Knop‐Gericke, Axel Schlicker, Lukas Doran, Andrew Kober, Delf Gurlo, Aleksander Penner, Simon Klötzer, Bernhard Angew Chem Int Ed Engl Communications C‐saturated Pd(0) nanoparticles with an extended phase boundary to ZrO(2) evolve from a Pd(0)Zr(0) precatalyst under CH(4) dry reforming conditions. This highly active catalyst state fosters bifunctional action: CO(2) is efficiently activated at oxidic phase boundary sites and Pd(x)C provides fast supply of C‐atoms toward the latter. John Wiley and Sons Inc. 2018-09-17 2018-10-26 /pmc/articles/PMC6221108/ /pubmed/30179293 http://dx.doi.org/10.1002/anie.201807463 Text en © 2018 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA. This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Köpfle, Norbert
Götsch, Thomas
Grünbacher, Matthias
Carbonio, Emilia A.
Hävecker, Michael
Knop‐Gericke, Axel
Schlicker, Lukas
Doran, Andrew
Kober, Delf
Gurlo, Aleksander
Penner, Simon
Klötzer, Bernhard
Zirconium‐Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming
title Zirconium‐Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming
title_full Zirconium‐Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming
title_fullStr Zirconium‐Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming
title_full_unstemmed Zirconium‐Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming
title_short Zirconium‐Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming
title_sort zirconium‐assisted activation of palladium to boost syngas production by methane dry reforming
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6221108/
https://www.ncbi.nlm.nih.gov/pubmed/30179293
http://dx.doi.org/10.1002/anie.201807463
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