Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water

We report the highly efficient and chemoselective oxidation of benzylic alcohols catalyzed by sodium copper chlorophyllin in water, producing corresponding arylcarbonyl compounds. Importantly, the catalytic system exhibits a wide substrate scope and high functional group tolerance. Moreover, seconda...

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Detalles Bibliográficos
Autores principales: Liu, Shi-juan, Zhang, Miao, Lu, Rong, Li, Xiu-ying, Che, Guang-bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6222594/
https://www.ncbi.nlm.nih.gov/pubmed/30060516
http://dx.doi.org/10.3390/molecules23081883
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author Liu, Shi-juan
Zhang, Miao
Lu, Rong
Li, Xiu-ying
Che, Guang-bo
author_facet Liu, Shi-juan
Zhang, Miao
Lu, Rong
Li, Xiu-ying
Che, Guang-bo
author_sort Liu, Shi-juan
collection PubMed
description We report the highly efficient and chemoselective oxidation of benzylic alcohols catalyzed by sodium copper chlorophyllin in water, producing corresponding arylcarbonyl compounds. Importantly, the catalytic system exhibits a wide substrate scope and high functional group tolerance. Moreover, secondary alcohols and even diarylmethanes were smoothly oxidized to the desired aryl ketones with excellent yields.
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spelling pubmed-62225942018-11-13 Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water Liu, Shi-juan Zhang, Miao Lu, Rong Li, Xiu-ying Che, Guang-bo Molecules Article We report the highly efficient and chemoselective oxidation of benzylic alcohols catalyzed by sodium copper chlorophyllin in water, producing corresponding arylcarbonyl compounds. Importantly, the catalytic system exhibits a wide substrate scope and high functional group tolerance. Moreover, secondary alcohols and even diarylmethanes were smoothly oxidized to the desired aryl ketones with excellent yields. MDPI 2018-07-27 /pmc/articles/PMC6222594/ /pubmed/30060516 http://dx.doi.org/10.3390/molecules23081883 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Liu, Shi-juan
Zhang, Miao
Lu, Rong
Li, Xiu-ying
Che, Guang-bo
Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water
title Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water
title_full Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water
title_fullStr Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water
title_full_unstemmed Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water
title_short Sodium Copper Chlorophyllin Catalyzed Chemoselective Oxidation of Benzylic Alcohols and Diarylmethanes in Water
title_sort sodium copper chlorophyllin catalyzed chemoselective oxidation of benzylic alcohols and diarylmethanes in water
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6222594/
https://www.ncbi.nlm.nih.gov/pubmed/30060516
http://dx.doi.org/10.3390/molecules23081883
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