Synthesis and Structural Identification of a Biaryl Ether-Linked Zearalenone Dimer

A new dimer of the food-relevant mycotoxin zearalenone was isolated after electrochemical and chemical oxidation. The structure was determined as a 16-O-15′-biaryl ether-linked dimer based on spectroscopic analyses ((1)H- and (13)C-NMR, COSY, HMBC, and HSQCAD) and high-resolution mass spectrometry a...

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Detalles Bibliográficos
Autores principales: Keller, Julia, Hantschke, Luisa, Haase, Hajo, Koch, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Technical Note
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6222810/
https://www.ncbi.nlm.nih.gov/pubmed/30322096
http://dx.doi.org/10.3390/molecules23102624
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author Keller, Julia
Hantschke, Luisa
Haase, Hajo
Koch, Matthias
author_facet Keller, Julia
Hantschke, Luisa
Haase, Hajo
Koch, Matthias
author_sort Keller, Julia
collection PubMed
description A new dimer of the food-relevant mycotoxin zearalenone was isolated after electrochemical and chemical oxidation. The structure was determined as a 16-O-15′-biaryl ether-linked dimer based on spectroscopic analyses ((1)H- and (13)C-NMR, COSY, HMBC, and HSQCAD) and high-resolution mass spectrometry analysis (Q-TOF).
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spelling pubmed-62228102018-11-13 Synthesis and Structural Identification of a Biaryl Ether-Linked Zearalenone Dimer Keller, Julia Hantschke, Luisa Haase, Hajo Koch, Matthias Molecules Technical Note A new dimer of the food-relevant mycotoxin zearalenone was isolated after electrochemical and chemical oxidation. The structure was determined as a 16-O-15′-biaryl ether-linked dimer based on spectroscopic analyses ((1)H- and (13)C-NMR, COSY, HMBC, and HSQCAD) and high-resolution mass spectrometry analysis (Q-TOF). MDPI 2018-10-12 /pmc/articles/PMC6222810/ /pubmed/30322096 http://dx.doi.org/10.3390/molecules23102624 Text en © 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Technical Note
Keller, Julia
Hantschke, Luisa
Haase, Hajo
Koch, Matthias
Synthesis and Structural Identification of a Biaryl Ether-Linked Zearalenone Dimer
title Synthesis and Structural Identification of a Biaryl Ether-Linked Zearalenone Dimer
title_full Synthesis and Structural Identification of a Biaryl Ether-Linked Zearalenone Dimer
title_fullStr Synthesis and Structural Identification of a Biaryl Ether-Linked Zearalenone Dimer
title_full_unstemmed Synthesis and Structural Identification of a Biaryl Ether-Linked Zearalenone Dimer
title_short Synthesis and Structural Identification of a Biaryl Ether-Linked Zearalenone Dimer
title_sort synthesis and structural identification of a biaryl ether-linked zearalenone dimer
topic Technical Note
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6222810/
https://www.ncbi.nlm.nih.gov/pubmed/30322096
http://dx.doi.org/10.3390/molecules23102624
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