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Massive Stokes shift in 12-coordinate Ce(NO2)(6)(3−): crystal structure, vibrational and electronic spectra
The Ce(3+) ion in Cs(2)NaCe(NO(2))(6) (I), which comprises the unusual T(h) site symmetry of the Ce(NO(2))(6)(3−) ion, demonstrates the largest Ce-O Stokes shift of 8715 cm(−1) and the low emission quenching temperature of 53 K. The activation energy for quenching changes with temperature, attribute...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6224556/ https://www.ncbi.nlm.nih.gov/pubmed/30409997 http://dx.doi.org/10.1038/s41598-018-34889-4 |