Cargando…

Further Studies on the Pyrolytic Domino Cyclization of Stabilized Phosphonium Ylides Bearing an Ortho-Aminophenyl Group

Four new, stabilized phosphonium ylides containing a 2-(benzyl(methyl)amino)phenyl group have been prepared and characterized and are found, upon pyrolysis under gas-phase flow conditions, to lose Ph(3)PO and benzyl radicals to afford new heterocyclic products resulting from domino cyclization of bo...

Descripción completa

Detalles Bibliográficos
Autores principales:	Aitken, R. Alan, Murray, Lorna, Slawin, Alexandra M. Z.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2018
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6225108/ https://www.ncbi.nlm.nih.gov/pubmed/30150585 http://dx.doi.org/10.3390/molecules23092153

Ejemplares similares

Ammonium Ylide Mediated Cyclization Reactions
por: Roiser, Lukas, et al.
Publicado: (2018)

Chemospecific Cyclizations of α‐Carbonyl Sulfoxonium Ylides on Aryls and Heteroaryls
por: Clare, Daniel, et al.
Publicado: (2019)

Synthesis of 4H‐Benzo[e][1,3]oxazin‐4‐ones by a Carbonylation–Cyclization Domino Reaction of ortho‐Halophenols and Cyanamide
por: Åkerbladh, Linda, et al.
Publicado: (2017)

Synthesis of 4H‐Benzo[e][1,3]oxazin‐4‐ones by a Carbonylation–Cyclization Domino Reaction of ortho‐Halophenols and Cyanamide
por: Åkerbladh, Linda, et al.
Publicado: (2017)

Triphenyltin Ortho-Aminophenyl- and 2-Pyridyl-Thiolates: Synthesis and In Vitro Antitumour Activity
por: Gielen, Marcel, et al.
Publicado: (1996)

CIDNP as a tool to unveil the reaction mechanism: interaction of mixed phosphonium–iodonium ylide with p-methoxyphenylacetylene
por: Levina, Irina I., et al.
Publicado: (2019)

Gold(I)-catalyzed domino cyclization for the synthesis of polyaromatic heterocycles
por: Morin, Mathieu, et al.
Publicado: (2013)

Metal-free visible light photoredox enables generation of carbyne equivalents via phosphonium ylide C–H activation
por: Das, Mrinmoy, et al.
Publicado: (2018)

Synthesis of (–)-Indolizidine 167B based on domino hydroformylation/cyclization reactions
por: Guazzelli, Giuditta, et al.
Publicado: (2008)

Total Synthesis of Cyclopiamide A Using Palladium-Catalyzed Domino Cyclization
por: Park, Sunhwa, et al.
Publicado: (2020)

Access to Diarylmethanols by Wittig Rearrangement of ortho-, meta-, and para-Benzyloxy-N-Butylbenzamides
por: Aitken, R. Alan, et al.
Publicado: (2022)

Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers
por: Viñas-Lóbez, Júlia, et al.
Publicado: (2021)

Unexpected cyclization of ortho-nitrochalcones into 2-alkylideneindolin-3-ones
por: Aksenov, Nicolai A., et al.
Publicado: (2020)

Versatile Dibenzothio[seleno]phenes via Hexadehydro-Diels–Alder Domino Cyclization
por: Liu, Baohua, et al.
Publicado: (2019)

Lewis acid–catalyzed domino generation/[2,3]-sigmatropic rearrangement of ammonium ylides to access chiral azabicycles
por: Xi, Song, et al.
Publicado: (2021)

Cooperative Catalysis for the Highly Diastereo‐ and Enantioselective [4+3]‐Cycloannulation of ortho‐Quinone Methides and Carbonyl Ylides
por: Suneja, Arun, et al.
Publicado: (2020)

Front Cover: Synthesis of 4H‐Benzo[e][1,3]oxazin‐4‐ones by a Carbonylation–Cyclization Domino Reaction of ortho‐Halophenols and Cyanamide (ChemistryOpen 5/2017)
por: Åkerbladh, Linda, et al.
Publicado: (2017)

Post-Ugi gold-catalyzed diastereoselective domino cyclization for the synthesis of diversely substituted spiroindolines
por: Kumar, Amit, et al.
Publicado: (2013)

Hypervalent Iodine(III)-Induced Domino Oxidative Cyclization for the Synthesis of Cyclopenta[b]furans
por: Lin, Mei-Huey, et al.
Publicado: (2016)

Photoredox Catalytic Pentafluorosulfanylative Domino Cyclization of α‐Substituted Alkenes to Oxaheterocycles by Using SF(6)
por: Rombach, David, et al.
Publicado: (2021)

Oxidative Cyclization of 4-(2-Aminophenyl)-4-oxo-2-phenylbutanenitriles into 2-(3-Oxoindolin-2-ylidene)acetonitriles
por: Aksenov, Nicolai A., et al.
Publicado: (2022)

Synthesis and Chemiluminescent Properties of Amino-Acylated luminol Derivatives Bearing Phosphonium Cations
por: Pantelia, Anna, et al.
Publicado: (2019)

Using Ylide Functionalization to Stabilize Boron Cations
por: Scherpf, Thorsten, et al.
Publicado: (2017)

Relating alkaline stability to the structure of quaternary phosphonium cations
por: Zhang, Bingzi, et al.
Publicado: (2018)

Cyclization of ortho-hydroxycinnamates to coumarins under mild conditions: A nucleophilic organocatalysis approach
por: Boeck, Florian, et al.
Publicado: (2012)

Enantioselective Catalytic [4+1]‐Cyclization of ortho‐Hydroxy‐para‐Quinone Methides with Allenoates
por: Zielke, Katharina, et al.
Publicado: (2019)

Mn-mediated sequential three-component domino Knoevenagel/cyclization/Michael addition/oxidative cyclization reaction towards annulated imidazo[1,2-a]pyridines
por: Storozhenko, Olga A, et al.
Publicado: (2018)

[1,5]-Hydride Shift-Cyclization versus C(sp(2))-H Functionalization in the Knoevenagel-Cyclization Domino Reactions of 1,4- and 1,5-Benzoxazepines
por: Szalóki Vargáné, Dóra, et al.
Publicado: (2020)

Palladium(II) Catalyzed Cyclization-Carbonylation-Cyclization Coupling Reaction of (ortho-Alkynyl Phenyl) (Methoxymethyl) Sulfides Using Molecular Oxygen as the Terminal Oxidant
por: Shen, Rong, et al.
Publicado: (2016)

Stereoselective Synthesis of Atropisomeric Acridinium Salts by the Catalyst‐Controlled Cyclization of ortho‐Quinone Methide Iminiums
por: Wu, Xingxing, et al.
Publicado: (2022)

Phosphonium-Templated Iodoplumbates
por: Omahen, Emily H., et al.
Publicado: (2018)

Enantioselective Stereodivergent Nucleophile‐Dependent Isothiourea‐Catalysed Domino Reactions
por: Matviitsuk, Anastassia, et al.
Publicado: (2016)

Sterically Hindered Phosphonium Salts: Structure, Properties and Palladium Nanoparticle Stabilization
por: Arkhipova, Daria M., et al.
Publicado: (2020)

Quinazolinone Synthesis through Base-Promoted S(N)Ar Reaction of ortho-Fluorobenzamides with Amides Followed by Cyclization
por: Iqbal, Muhammad Asif, et al.
Publicado: (2019)

Oxidative Cyclization at ortho-Position of Phenol: Improved Total Synthesis of 3-(Phenethylamino)demethyl(oxy)aaptamine
por: Nakatani, Yuki, et al.
Publicado: (2023)

Asymmetric Synthesis of Tetrahydropyridines via an Organocatalytic One-Pot Multicomponent Michael/Aza-Henry/Cyclization Triple Domino Reaction
por: Blümel, Marcus, et al.
Publicado: (2014)

Dominó
por: King, Ross, 1962-
Publicado: (1996)

Dominoes
por: Petsko, Gregory A
Publicado: (2011)

Cyclic phosphonium ionic liquids
por: Lall-Ramnarine, Sharon I, et al.
Publicado: (2014)

Synthesis of Novel 1,4-Diketone Derivatives and Their Further Cyclization
por: Can Üsküp, Hacer, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_9ia5lqqm747ge5tl4f90nejch5