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Transition-Metal-Free Activation of Amide Bond by Arynes
Highly reactive arynes activate the N–C and C=O bonds of amide groups under transition metal-free conditions. This review highlights the insertion of arynes into the N–C and C=O bonds of the amide group. The insertion of arynes into the N–C bond gives the unstable four-membered ring intermediates, w...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6225192/ https://www.ncbi.nlm.nih.gov/pubmed/30150534 http://dx.doi.org/10.3390/molecules23092145 |