Characterisation, electrochemical and oxidative addition data of organophosphorus-containing rhodium(I) complexes

This data article contains the (1)H Nuclear Magnetic Resonance (NMR), ultraviolet and visible (UV–vis) and Attenuated Total Reflectance Fourier Transformed Infra-red (ATR FTIR) characterization of a series of organophosphorus-containing rhodium(I) complexes. The electrochemical data acquired by mean...

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Detalles Bibliográficos
Autores principales: Manana, P.S., Erasmus, E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6234413/
https://www.ncbi.nlm.nih.gov/pubmed/30456263
http://dx.doi.org/10.1016/j.dib.2018.10.103
Descripción
Sumario:This data article contains the (1)H Nuclear Magnetic Resonance (NMR), ultraviolet and visible (UV–vis) and Attenuated Total Reflectance Fourier Transformed Infra-red (ATR FTIR) characterization of a series of organophosphorus-containing rhodium(I) complexes. The electrochemical data acquired by means of cyclic voltammetry of the three organophosphorus-containing ligands (with the structure C(6)H(5)XPPh(2), where X = O, S and NH) and their acetylacetonato (monocarbonyl) organophosphorus rhodium(I) compounds, [Rh(acac)CO(C(6)H(5)XPPh(2))] are reported. Additionally, the kinetic data of the oxidative addition of methyl iodide to the rhodium(I) complexes, are also presented.

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