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Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen
[Image: see text] The synthesis and characterization of five-coordinate rhodium(III) and iridium(III) 2,2′-biphenyl complexes [M(CNC-12)(biph)][BAr(F)(4)] (M = Rh (1a), Ir (1b)), featuring the macrocyclic lutidine- and NHC-based pincer ligand CNC-12 are reported. In the solid state these complexes a...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6234485/ https://www.ncbi.nlm.nih.gov/pubmed/30449914 http://dx.doi.org/10.1021/acs.organomet.8b00595 |