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A Chiral Bipyrimidine-Bridged Dy(2) SMM: A Comparative Experimental and Theoretical Study of the Correlation Between the Distortion of the DyO6N2 Coordination Sphere and the Anisotropy Barrier
Chiral bipyrimidine-bridged dinuclear Ln(III) complexes of general formula [(μ-bipym){((+)-tfacam)(3)Ln}(2)] and [(μ-bipym){((-)-tfacam)(3)Ln}(2)], have been prepared from the assembly of Ln(AcO)(3)·nH(2)O (Ln(III) = Dy, Gd), (+)/(−)-3-(trifluoroacetyl)camphor enantiopure ligands ((+)/(-)-Htfacam) a...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Frontiers Media S.A.
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236069/ https://www.ncbi.nlm.nih.gov/pubmed/30467538 http://dx.doi.org/10.3389/fchem.2018.00537 |