One-Pot Preparations of Diaryliodonium Bromides from Iodoarenes and Arenes, with Sodium Perborate as the Oxidant(†)

This paper reports a one-pot synthesis of the title bromides from both activated and deactivated iodoarenes which are first oxidized with anhydrous NaBO(3)·H(2)O/Ac(2)O/conc.H(2)SO(4) liquid mixtures, then coupled in situ with benzene and activated arenes and, finally, precipitated out with a KBr so...

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Detalles Bibliográficos
Autores principales: Kryska, Anna, Skulski, Lech
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2001
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236341/
http://dx.doi.org/10.3390/61100875
Descripción
Sumario:This paper reports a one-pot synthesis of the title bromides from both activated and deactivated iodoarenes which are first oxidized with anhydrous NaBO(3)·H(2)O/Ac(2)O/conc.H(2)SO(4) liquid mixtures, then coupled in situ with benzene and activated arenes and, finally, precipitated out with a KBr solution; this method is easy, cheap, safe and fairly effective.

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