One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant(†)

Ten representative (dichloroiodo)arenes, ArICl(2), were prepared from the corresponding arenes and diiodine in variable anhydrous mixtures, ArH/I(2)/CrO(3)/AcOH/Ac(2)O/conc. H(2)SO(4), followed by the addition of conc. hydrochloric acid, used as the source of chlorine; ArICl(2) are useful in organic...

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Detalles Bibliográficos
Autores principales: Obeid, Nicolas, Skulski, Lech
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2001
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236342/
http://dx.doi.org/10.3390/61100869
Descripción
Sumario:Ten representative (dichloroiodo)arenes, ArICl(2), were prepared from the corresponding arenes and diiodine in variable anhydrous mixtures, ArH/I(2)/CrO(3)/AcOH/Ac(2)O/conc. H(2)SO(4), followed by the addition of conc. hydrochloric acid, used as the source of chlorine; ArICl(2) are useful in organic synthesis as mild and selective chlorinating and/or oxidizing agents.

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