One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant(†)

Ten representative (dichloroiodo)arenes, ArICl(2), were prepared from the corresponding arenes and diiodine in variable anhydrous mixtures, ArH/I(2)/CrO(3)/AcOH/Ac(2)O/conc. H(2)SO(4), followed by the addition of conc. hydrochloric acid, used as the source of chlorine; ArICl(2) are useful in organic...

Descripción completa

Detalles Bibliográficos
Autores principales: Obeid, Nicolas, Skulski, Lech
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2001
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236342/
http://dx.doi.org/10.3390/61100869
_version_ 1783371015877820416
author Obeid, Nicolas
Skulski, Lech
author_facet Obeid, Nicolas
Skulski, Lech
author_sort Obeid, Nicolas
collection PubMed
description Ten representative (dichloroiodo)arenes, ArICl(2), were prepared from the corresponding arenes and diiodine in variable anhydrous mixtures, ArH/I(2)/CrO(3)/AcOH/Ac(2)O/conc. H(2)SO(4), followed by the addition of conc. hydrochloric acid, used as the source of chlorine; ArICl(2) are useful in organic synthesis as mild and selective chlorinating and/or oxidizing agents.
format Online
Article
Text
id pubmed-6236342
institution National Center for Biotechnology Information
language English
publishDate 2001
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-62363422018-11-19 One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant(†) Obeid, Nicolas Skulski, Lech Molecules Article Ten representative (dichloroiodo)arenes, ArICl(2), were prepared from the corresponding arenes and diiodine in variable anhydrous mixtures, ArH/I(2)/CrO(3)/AcOH/Ac(2)O/conc. H(2)SO(4), followed by the addition of conc. hydrochloric acid, used as the source of chlorine; ArICl(2) are useful in organic synthesis as mild and selective chlorinating and/or oxidizing agents. MDPI 2001-10-31 /pmc/articles/PMC6236342/ http://dx.doi.org/10.3390/61100869 Text en © 2001 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Obeid, Nicolas
Skulski, Lech
One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant(†)
title One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant(†)
title_full One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant(†)
title_fullStr One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant(†)
title_full_unstemmed One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant(†)
title_short One-Pot Procedures for Preparing (Dichloroiodo)arenes from Arenes and Diiodine, with Chromium(VI) Oxide as the Oxidant(†)
title_sort one-pot procedures for preparing (dichloroiodo)arenes from arenes and diiodine, with chromium(vi) oxide as the oxidant(†)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236342/
http://dx.doi.org/10.3390/61100869
work_keys_str_mv AT obeidnicolas onepotproceduresforpreparingdichloroiodoarenesfromarenesanddiiodinewithchromiumvioxideastheoxidant
AT skulskilech onepotproceduresforpreparingdichloroiodoarenesfromarenesanddiiodinewithchromiumvioxideastheoxidant

Ejemplares similares