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Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant†

- Easy, safe, and effective novel methods for preparing either (diacetoxyiodo)-arenes, ArI(OAc)(2), or iodylarenes, ArIO(2), from the corresponding iodoarenes, ArI, using sodium periodate as the oxidant are presented in this paper. In order to obtain 2- and 4-iodylbenzoic acids, the respective sodiu...

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Autores principales: Kazmierczak, Pawel, Skulski, Lech, Kraszkiewicz, Lukasz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2001
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236348/
http://dx.doi.org/10.3390/61100881
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author Kazmierczak, Pawel
Skulski, Lech
Kraszkiewicz, Lukasz
author_facet Kazmierczak, Pawel
Skulski, Lech
Kraszkiewicz, Lukasz
author_sort Kazmierczak, Pawel
collection PubMed
description - Easy, safe, and effective novel methods for preparing either (diacetoxyiodo)-arenes, ArI(OAc)(2), or iodylarenes, ArIO(2), from the corresponding iodoarenes, ArI, using sodium periodate as the oxidant are presented in this paper. In order to obtain 2- and 4-iodylbenzoic acids, the respective sodium salts of 2- and 4-iodobenzoic acids should be used as the starting substrates, because mixtures containing the corresponding iodosyl derivatives as the main products along with the intended iodyl compounds are produced from the free parent acids.
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spelling pubmed-62363482018-11-19 Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant† Kazmierczak, Pawel Skulski, Lech Kraszkiewicz, Lukasz Molecules Article - Easy, safe, and effective novel methods for preparing either (diacetoxyiodo)-arenes, ArI(OAc)(2), or iodylarenes, ArIO(2), from the corresponding iodoarenes, ArI, using sodium periodate as the oxidant are presented in this paper. In order to obtain 2- and 4-iodylbenzoic acids, the respective sodium salts of 2- and 4-iodobenzoic acids should be used as the starting substrates, because mixtures containing the corresponding iodosyl derivatives as the main products along with the intended iodyl compounds are produced from the free parent acids. MDPI 2001-10-31 /pmc/articles/PMC6236348/ http://dx.doi.org/10.3390/61100881 Text en © 2001 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Kazmierczak, Pawel
Skulski, Lech
Kraszkiewicz, Lukasz
Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant†
title Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant†
title_full Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant†
title_fullStr Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant†
title_full_unstemmed Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant†
title_short Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant†
title_sort syntheses of (diacetoxyiodo)arenes or iodylarenes from iodoarenes, with sodium periodate as the oxidant†
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236348/
http://dx.doi.org/10.3390/61100881
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