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Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant†
- Easy, safe, and effective novel methods for preparing either (diacetoxyiodo)-arenes, ArI(OAc)(2), or iodylarenes, ArIO(2), from the corresponding iodoarenes, ArI, using sodium periodate as the oxidant are presented in this paper. In order to obtain 2- and 4-iodylbenzoic acids, the respective sodiu...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2001
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236348/ http://dx.doi.org/10.3390/61100881 |
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author | Kazmierczak, Pawel Skulski, Lech Kraszkiewicz, Lukasz |
author_facet | Kazmierczak, Pawel Skulski, Lech Kraszkiewicz, Lukasz |
author_sort | Kazmierczak, Pawel |
collection | PubMed |
description | - Easy, safe, and effective novel methods for preparing either (diacetoxyiodo)-arenes, ArI(OAc)(2), or iodylarenes, ArIO(2), from the corresponding iodoarenes, ArI, using sodium periodate as the oxidant are presented in this paper. In order to obtain 2- and 4-iodylbenzoic acids, the respective sodium salts of 2- and 4-iodobenzoic acids should be used as the starting substrates, because mixtures containing the corresponding iodosyl derivatives as the main products along with the intended iodyl compounds are produced from the free parent acids. |
format | Online Article Text |
id | pubmed-6236348 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2001 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-62363482018-11-19 Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant† Kazmierczak, Pawel Skulski, Lech Kraszkiewicz, Lukasz Molecules Article - Easy, safe, and effective novel methods for preparing either (diacetoxyiodo)-arenes, ArI(OAc)(2), or iodylarenes, ArIO(2), from the corresponding iodoarenes, ArI, using sodium periodate as the oxidant are presented in this paper. In order to obtain 2- and 4-iodylbenzoic acids, the respective sodium salts of 2- and 4-iodobenzoic acids should be used as the starting substrates, because mixtures containing the corresponding iodosyl derivatives as the main products along with the intended iodyl compounds are produced from the free parent acids. MDPI 2001-10-31 /pmc/articles/PMC6236348/ http://dx.doi.org/10.3390/61100881 Text en © 2001 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes. |
spellingShingle | Article Kazmierczak, Pawel Skulski, Lech Kraszkiewicz, Lukasz Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant† |
title | Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant† |
title_full | Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant† |
title_fullStr | Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant† |
title_full_unstemmed | Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant† |
title_short | Syntheses of (Diacetoxyiodo)arenes or Iodylarenes from Iodoarenes, with Sodium Periodate as the Oxidant† |
title_sort | syntheses of (diacetoxyiodo)arenes or iodylarenes from iodoarenes, with sodium periodate as the oxidant† |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236348/ http://dx.doi.org/10.3390/61100881 |
work_keys_str_mv | AT kazmierczakpawel synthesesofdiacetoxyiodoarenesoriodylarenesfromiodoareneswithsodiumperiodateastheoxidant AT skulskilech synthesesofdiacetoxyiodoarenesoriodylarenesfromiodoareneswithsodiumperiodateastheoxidant AT kraszkiewiczlukasz synthesesofdiacetoxyiodoarenesoriodylarenesfromiodoareneswithsodiumperiodateastheoxidant |