Synthesis of 5-(4-X-Phenyl)-10,15,20-tris(Substituted Phenyl) Porphyrins Using Dipyrromethanes

5-(4-X-Phenyl)-10,15,20-tris(substituted phenyl) porphyrins (4-6) were synthesized from meso-(substituted phenyl) dipyrromethanes (1-3), which in turn were prepared in yields of 75-92 %. This synthetic pathway was compared with the binary mixed aldehyde and pyrrole condensation method. The reported...

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Autor principal: Durantini, Edgardo N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2001
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236351/
http://dx.doi.org/10.3390/60600533
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author Durantini, Edgardo N.
author_facet Durantini, Edgardo N.
author_sort Durantini, Edgardo N.
collection PubMed
description 5-(4-X-Phenyl)-10,15,20-tris(substituted phenyl) porphyrins (4-6) were synthesized from meso-(substituted phenyl) dipyrromethanes (1-3), which in turn were prepared in yields of 75-92 %. This synthetic pathway was compared with the binary mixed aldehyde and pyrrole condensation method. The reported dipyrromethane approach is advantageous for porphyrins substituted by –OCH(3) (4) and -F (6) groups (12-14 %), while the yield of porphyrins bearing –N(CH(3))(2) (5) groups was similar (~0.3 %) by both methods.
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spelling pubmed-62363512018-11-19 Synthesis of 5-(4-X-Phenyl)-10,15,20-tris(Substituted Phenyl) Porphyrins Using Dipyrromethanes Durantini, Edgardo N. Molecules Article 5-(4-X-Phenyl)-10,15,20-tris(substituted phenyl) porphyrins (4-6) were synthesized from meso-(substituted phenyl) dipyrromethanes (1-3), which in turn were prepared in yields of 75-92 %. This synthetic pathway was compared with the binary mixed aldehyde and pyrrole condensation method. The reported dipyrromethane approach is advantageous for porphyrins substituted by –OCH(3) (4) and -F (6) groups (12-14 %), while the yield of porphyrins bearing –N(CH(3))(2) (5) groups was similar (~0.3 %) by both methods. MDPI 2001-05-31 /pmc/articles/PMC6236351/ http://dx.doi.org/10.3390/60600533 Text en © 2001 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes
spellingShingle Article
Durantini, Edgardo N.
Synthesis of 5-(4-X-Phenyl)-10,15,20-tris(Substituted Phenyl) Porphyrins Using Dipyrromethanes
title Synthesis of 5-(4-X-Phenyl)-10,15,20-tris(Substituted Phenyl) Porphyrins Using Dipyrromethanes
title_full Synthesis of 5-(4-X-Phenyl)-10,15,20-tris(Substituted Phenyl) Porphyrins Using Dipyrromethanes
title_fullStr Synthesis of 5-(4-X-Phenyl)-10,15,20-tris(Substituted Phenyl) Porphyrins Using Dipyrromethanes
title_full_unstemmed Synthesis of 5-(4-X-Phenyl)-10,15,20-tris(Substituted Phenyl) Porphyrins Using Dipyrromethanes
title_short Synthesis of 5-(4-X-Phenyl)-10,15,20-tris(Substituted Phenyl) Porphyrins Using Dipyrromethanes
title_sort synthesis of 5-(4-x-phenyl)-10,15,20-tris(substituted phenyl) porphyrins using dipyrromethanes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236351/
http://dx.doi.org/10.3390/60600533
work_keys_str_mv AT durantiniedgardon synthesisof54xphenyl101520trissubstitutedphenylporphyrinsusingdipyrromethanes

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