Facile and Fast Pinacol Rearrangement by AlCl(3) in the Solid State

A facile and efficient synthetic procedure for effecting the pinacol rearrangement catalyzed by AlCl(3) in the absence of solvent is developed. The rearrangement product is obtained at room temperature in a few minutes and in almost quantitative yield. Benzylic pinacols rearrange under these conditi...

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Detalles Bibliográficos
Autores principales: Rashidi-Ranjbar, Parviz, Kianmehr, Ebrahim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2001
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236384/
http://dx.doi.org/10.3390/60500442
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author Rashidi-Ranjbar, Parviz
Kianmehr, Ebrahim
author_facet Rashidi-Ranjbar, Parviz
Kianmehr, Ebrahim
author_sort Rashidi-Ranjbar, Parviz
collection PubMed
description A facile and efficient synthetic procedure for effecting the pinacol rearrangement catalyzed by AlCl(3) in the absence of solvent is developed. The rearrangement product is obtained at room temperature in a few minutes and in almost quantitative yield. Benzylic pinacols rearrange under these conditions, while aliphatic pinacols do not react.
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spelling pubmed-62363842018-11-20 Facile and Fast Pinacol Rearrangement by AlCl(3) in the Solid State Rashidi-Ranjbar, Parviz Kianmehr, Ebrahim Molecules Article A facile and efficient synthetic procedure for effecting the pinacol rearrangement catalyzed by AlCl(3) in the absence of solvent is developed. The rearrangement product is obtained at room temperature in a few minutes and in almost quantitative yield. Benzylic pinacols rearrange under these conditions, while aliphatic pinacols do not react. MDPI 2001-04-30 /pmc/articles/PMC6236384/ http://dx.doi.org/10.3390/60500442 Text en © 2001 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes
spellingShingle Article
Rashidi-Ranjbar, Parviz
Kianmehr, Ebrahim
Facile and Fast Pinacol Rearrangement by AlCl(3) in the Solid State
title Facile and Fast Pinacol Rearrangement by AlCl(3) in the Solid State
title_full Facile and Fast Pinacol Rearrangement by AlCl(3) in the Solid State
title_fullStr Facile and Fast Pinacol Rearrangement by AlCl(3) in the Solid State
title_full_unstemmed Facile and Fast Pinacol Rearrangement by AlCl(3) in the Solid State
title_short Facile and Fast Pinacol Rearrangement by AlCl(3) in the Solid State
title_sort facile and fast pinacol rearrangement by alcl(3) in the solid state
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236384/
http://dx.doi.org/10.3390/60500442
work_keys_str_mv AT rashidiranjbarparviz facileandfastpinacolrearrangementbyalcl3inthesolidstate
AT kianmehrebrahim facileandfastpinacolrearrangementbyalcl3inthesolidstate

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