Novel Chiral Switching Ligands for Enantioselective Asymmetric Reductions of Prochiral Ketones

The newly developed chiral ligands 1 and 4 show opposite enantioselectivity in the asymmetric reduction of prochiral ketones resulting in the production of either enantiomer depending on the metal complex with high enantiomeric excess.

Detalles Bibliográficos
Autores principales: Narasimhan, S., Swarnalakshmi, S., Balakumar, R., Velmathi, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2001
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236386/
http://dx.doi.org/10.3390/61200988
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author Narasimhan, S.
Swarnalakshmi, S.
Balakumar, R.
Velmathi, S.
author_facet Narasimhan, S.
Swarnalakshmi, S.
Balakumar, R.
Velmathi, S.
author_sort Narasimhan, S.
collection PubMed
description The newly developed chiral ligands 1 and 4 show opposite enantioselectivity in the asymmetric reduction of prochiral ketones resulting in the production of either enantiomer depending on the metal complex with high enantiomeric excess.
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spelling pubmed-62363862018-11-20 Novel Chiral Switching Ligands for Enantioselective Asymmetric Reductions of Prochiral Ketones Narasimhan, S. Swarnalakshmi, S. Balakumar, R. Velmathi, S. Molecules Article The newly developed chiral ligands 1 and 4 show opposite enantioselectivity in the asymmetric reduction of prochiral ketones resulting in the production of either enantiomer depending on the metal complex with high enantiomeric excess. MDPI 2001-11-30 /pmc/articles/PMC6236386/ http://dx.doi.org/10.3390/61200988 Text en © 2001 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Narasimhan, S.
Swarnalakshmi, S.
Balakumar, R.
Velmathi, S.
Novel Chiral Switching Ligands for Enantioselective Asymmetric Reductions of Prochiral Ketones
title Novel Chiral Switching Ligands for Enantioselective Asymmetric Reductions of Prochiral Ketones
title_full Novel Chiral Switching Ligands for Enantioselective Asymmetric Reductions of Prochiral Ketones
title_fullStr Novel Chiral Switching Ligands for Enantioselective Asymmetric Reductions of Prochiral Ketones
title_full_unstemmed Novel Chiral Switching Ligands for Enantioselective Asymmetric Reductions of Prochiral Ketones
title_short Novel Chiral Switching Ligands for Enantioselective Asymmetric Reductions of Prochiral Ketones
title_sort novel chiral switching ligands for enantioselective asymmetric reductions of prochiral ketones
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236386/
http://dx.doi.org/10.3390/61200988
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AT balakumarr novelchiralswitchingligandsforenantioselectiveasymmetricreductionsofprochiralketones
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