Applications of Microwave in Organic Synthesis: An Improved One-step Synthesis of Metallophthalocyanines and a New Modified Microwave Oven for Dry Reactions †

Metallophthalocyanine complexes are obtained quickly and efficiently by the reaction of phthalodinitrile with hydrated metallic salts without solvent and under microwave irradiation. The use of a modified commercial microwave oven to perform this type of reactions under dry conditions is described....

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Autores principales: Villemin, Didier, Hammadi, Mohamed, Hachemi, Messaoud, Bar, Nathalie
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2001
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236420/
http://dx.doi.org/10.3390/61000831
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author Villemin, Didier
Hammadi, Mohamed
Hachemi, Messaoud
Bar, Nathalie
author_facet Villemin, Didier
Hammadi, Mohamed
Hachemi, Messaoud
Bar, Nathalie
author_sort Villemin, Didier
collection PubMed
description Metallophthalocyanine complexes are obtained quickly and efficiently by the reaction of phthalodinitrile with hydrated metallic salts without solvent and under microwave irradiation. The use of a modified commercial microwave oven to perform this type of reactions under dry conditions is described. Metallophthalocyanines and metallododecachlorophthalocyanines of some divalent metals can be also obtained from phthalic or tetrachlorophthalic anhydrides with hydrated metallic salt and urea under microwave irradiation and without solvent.
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spelling pubmed-62364202018-11-19 Applications of Microwave in Organic Synthesis: An Improved One-step Synthesis of Metallophthalocyanines and a New Modified Microwave Oven for Dry Reactions † Villemin, Didier Hammadi, Mohamed Hachemi, Messaoud Bar, Nathalie Molecules Article Metallophthalocyanine complexes are obtained quickly and efficiently by the reaction of phthalodinitrile with hydrated metallic salts without solvent and under microwave irradiation. The use of a modified commercial microwave oven to perform this type of reactions under dry conditions is described. Metallophthalocyanines and metallododecachlorophthalocyanines of some divalent metals can be also obtained from phthalic or tetrachlorophthalic anhydrides with hydrated metallic salt and urea under microwave irradiation and without solvent. MDPI 2001-10-31 /pmc/articles/PMC6236420/ http://dx.doi.org/10.3390/61000831 Text en © 2001 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Villemin, Didier
Hammadi, Mohamed
Hachemi, Messaoud
Bar, Nathalie
Applications of Microwave in Organic Synthesis: An Improved One-step Synthesis of Metallophthalocyanines and a New Modified Microwave Oven for Dry Reactions †
title Applications of Microwave in Organic Synthesis: An Improved One-step Synthesis of Metallophthalocyanines and a New Modified Microwave Oven for Dry Reactions †
title_full Applications of Microwave in Organic Synthesis: An Improved One-step Synthesis of Metallophthalocyanines and a New Modified Microwave Oven for Dry Reactions †
title_fullStr Applications of Microwave in Organic Synthesis: An Improved One-step Synthesis of Metallophthalocyanines and a New Modified Microwave Oven for Dry Reactions †
title_full_unstemmed Applications of Microwave in Organic Synthesis: An Improved One-step Synthesis of Metallophthalocyanines and a New Modified Microwave Oven for Dry Reactions †
title_short Applications of Microwave in Organic Synthesis: An Improved One-step Synthesis of Metallophthalocyanines and a New Modified Microwave Oven for Dry Reactions †
title_sort applications of microwave in organic synthesis: an improved one-step synthesis of metallophthalocyanines and a new modified microwave oven for dry reactions †
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236420/
http://dx.doi.org/10.3390/61000831
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