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An Efficient and Chemoselective Method for Oximination of β-Diketones Under Mild and Heterogeneous Conditions

A combination of oxalic acid dihydrate and sodium nitrite in the presence of wet SiO(2) was used as an effective nitrosating agent for the nitrosation of β-diketones to their corresponding α-oximinoketones in moderate to excellent yields under mild and heterogenous conditions.

Detalles Bibliográficos
Autor principal: Zolfigol, Mohammad Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2001
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236430/
http://dx.doi.org/10.3390/60800694
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author Zolfigol, Mohammad Ali
author_facet Zolfigol, Mohammad Ali
author_sort Zolfigol, Mohammad Ali
collection PubMed
description A combination of oxalic acid dihydrate and sodium nitrite in the presence of wet SiO(2) was used as an effective nitrosating agent for the nitrosation of β-diketones to their corresponding α-oximinoketones in moderate to excellent yields under mild and heterogenous conditions.
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spelling pubmed-62364302018-11-19 An Efficient and Chemoselective Method for Oximination of β-Diketones Under Mild and Heterogeneous Conditions Zolfigol, Mohammad Ali Molecules Article A combination of oxalic acid dihydrate and sodium nitrite in the presence of wet SiO(2) was used as an effective nitrosating agent for the nitrosation of β-diketones to their corresponding α-oximinoketones in moderate to excellent yields under mild and heterogenous conditions. MDPI 2001-07-31 /pmc/articles/PMC6236430/ http://dx.doi.org/10.3390/60800694 Text en © 2001 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Zolfigol, Mohammad Ali
An Efficient and Chemoselective Method for Oximination of β-Diketones Under Mild and Heterogeneous Conditions
title An Efficient and Chemoselective Method for Oximination of β-Diketones Under Mild and Heterogeneous Conditions
title_full An Efficient and Chemoselective Method for Oximination of β-Diketones Under Mild and Heterogeneous Conditions
title_fullStr An Efficient and Chemoselective Method for Oximination of β-Diketones Under Mild and Heterogeneous Conditions
title_full_unstemmed An Efficient and Chemoselective Method for Oximination of β-Diketones Under Mild and Heterogeneous Conditions
title_short An Efficient and Chemoselective Method for Oximination of β-Diketones Under Mild and Heterogeneous Conditions
title_sort efficient and chemoselective method for oximination of β-diketones under mild and heterogeneous conditions
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236430/
http://dx.doi.org/10.3390/60800694
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