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Synthesis of Polycyclic Ring Systems Using Transition Metal Catalyzed Cyclizations of Diazo Alkynyl Ketones ‡

The rhodium(II)-catalyzed reaction of α-diazo ketones bearing tethered alkyne units represents a new and useful method for the construction of a variety of substituted cyclopentenones. The process proceeds by addition of the rhodium-stabilized carbenoid onto the acetylenic π-bond to give a vinyl car...

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Detalles Bibliográficos
Autor principal:	Padwa, Albert
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2000
Materias:	Review
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236455/ http://dx.doi.org/10.3390/60100001

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