Zn Mediated Regioselective Barbier Reaction of Propargylic Bromides in THF/aq. NH(4)Cl Solution

The reaction of substituted and unsubstituted propargylic bromides with butanal in presence of zinc power in THF/saturated aqueous NH(4)Cl solution gave corresponding allenic and propargylic alcohols with high selectivity.

Detalles Bibliográficos
Autores principales: Jõgi, Artur, Mäeorg, Uno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2001
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236518/
http://dx.doi.org/10.3390/61200964
Descripción
Sumario:The reaction of substituted and unsubstituted propargylic bromides with butanal in presence of zinc power in THF/saturated aqueous NH(4)Cl solution gave corresponding allenic and propargylic alcohols with high selectivity.

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