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Zn Mediated Regioselective Barbier Reaction of Propargylic Bromides in THF/aq. NH(4)Cl Solution

The reaction of substituted and unsubstituted propargylic bromides with butanal in presence of zinc power in THF/saturated aqueous NH(4)Cl solution gave corresponding allenic and propargylic alcohols with high selectivity.

Detalles Bibliográficos
Autores principales: Jõgi, Artur, Mäeorg, Uno
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2001
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236518/
http://dx.doi.org/10.3390/61200964
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author Jõgi, Artur
Mäeorg, Uno
author_facet Jõgi, Artur
Mäeorg, Uno
author_sort Jõgi, Artur
collection PubMed
description The reaction of substituted and unsubstituted propargylic bromides with butanal in presence of zinc power in THF/saturated aqueous NH(4)Cl solution gave corresponding allenic and propargylic alcohols with high selectivity.
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spelling pubmed-62365182018-11-20 Zn Mediated Regioselective Barbier Reaction of Propargylic Bromides in THF/aq. NH(4)Cl Solution Jõgi, Artur Mäeorg, Uno Molecules Article The reaction of substituted and unsubstituted propargylic bromides with butanal in presence of zinc power in THF/saturated aqueous NH(4)Cl solution gave corresponding allenic and propargylic alcohols with high selectivity. MDPI 2001-11-30 /pmc/articles/PMC6236518/ http://dx.doi.org/10.3390/61200964 Text en © 2001 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Jõgi, Artur
Mäeorg, Uno
Zn Mediated Regioselective Barbier Reaction of Propargylic Bromides in THF/aq. NH(4)Cl Solution
title Zn Mediated Regioselective Barbier Reaction of Propargylic Bromides in THF/aq. NH(4)Cl Solution
title_full Zn Mediated Regioselective Barbier Reaction of Propargylic Bromides in THF/aq. NH(4)Cl Solution
title_fullStr Zn Mediated Regioselective Barbier Reaction of Propargylic Bromides in THF/aq. NH(4)Cl Solution
title_full_unstemmed Zn Mediated Regioselective Barbier Reaction of Propargylic Bromides in THF/aq. NH(4)Cl Solution
title_short Zn Mediated Regioselective Barbier Reaction of Propargylic Bromides in THF/aq. NH(4)Cl Solution
title_sort zn mediated regioselective barbier reaction of propargylic bromides in thf/aq. nh(4)cl solution
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6236518/
http://dx.doi.org/10.3390/61200964
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