RAFT polymer cross-coupling with boronic acids

The ability to modify the thiocarbonylthio end-groups of RAFT polymers is important for applications where an inert or highly functionalised material is required. Here we report a copper promoted cross-coupling reaction between RAFT polymer end-groups and aryl boronic acids. This method gives high c...

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Detalles Bibliográficos
Autores principales: Golf, Hartwig, O'Shea, Riley, Braybrook, Carl, Hutt, Oliver, Lupton, David W., Hooper, Joel F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6237125/
https://www.ncbi.nlm.nih.gov/pubmed/30542540
http://dx.doi.org/10.1039/c8sc01862f
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author Golf, Hartwig
O'Shea, Riley
Braybrook, Carl
Hutt, Oliver
Lupton, David W.
Hooper, Joel F.
author_facet Golf, Hartwig
O'Shea, Riley
Braybrook, Carl
Hutt, Oliver
Lupton, David W.
Hooper, Joel F.
author_sort Golf, Hartwig
collection PubMed
description The ability to modify the thiocarbonylthio end-groups of RAFT polymers is important for applications where an inert or highly functionalised material is required. Here we report a copper promoted cross-coupling reaction between RAFT polymer end-groups and aryl boronic acids. This method gives high conversion to the modified polymers, and is compatible with a wide variety of functional molecules.
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spelling pubmed-62371252018-12-12 RAFT polymer cross-coupling with boronic acids Golf, Hartwig O'Shea, Riley Braybrook, Carl Hutt, Oliver Lupton, David W. Hooper, Joel F. Chem Sci Chemistry The ability to modify the thiocarbonylthio end-groups of RAFT polymers is important for applications where an inert or highly functionalised material is required. Here we report a copper promoted cross-coupling reaction between RAFT polymer end-groups and aryl boronic acids. This method gives high conversion to the modified polymers, and is compatible with a wide variety of functional molecules. Royal Society of Chemistry 2018-07-18 /pmc/articles/PMC6237125/ /pubmed/30542540 http://dx.doi.org/10.1039/c8sc01862f Text en This journal is © The Royal Society of Chemistry 2018 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Golf, Hartwig
O'Shea, Riley
Braybrook, Carl
Hutt, Oliver
Lupton, David W.
Hooper, Joel F.
RAFT polymer cross-coupling with boronic acids
title RAFT polymer cross-coupling with boronic acids
title_full RAFT polymer cross-coupling with boronic acids
title_fullStr RAFT polymer cross-coupling with boronic acids
title_full_unstemmed RAFT polymer cross-coupling with boronic acids
title_short RAFT polymer cross-coupling with boronic acids
title_sort raft polymer cross-coupling with boronic acids
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6237125/
https://www.ncbi.nlm.nih.gov/pubmed/30542540
http://dx.doi.org/10.1039/c8sc01862f
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AT luptondavidw raftpolymercrosscouplingwithboronicacids
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