Mechanism of copper-free Sonogashira reaction operates through palladium-palladium transmetallation

The seminal contributions by Sonogashira, Cassar and Heck in mid 1970s on Pd/Cu- and Pd-catalysed (copper-free) coupling of acetylenes with aryl or vinyl halides have evolved in myriad applications. Despite the enormous success both in academia and in industry, however, critical mechanistic question...

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Detalles Bibliográficos
Autores principales: Gazvoda, Martin, Virant, Miha, Pinter, Balazs, Košmrlj, Janez
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6240041/
https://www.ncbi.nlm.nih.gov/pubmed/30446654
http://dx.doi.org/10.1038/s41467-018-07081-5

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6240041/
https://www.ncbi.nlm.nih.gov/pubmed/30446654
http://dx.doi.org/10.1038/s41467-018-07081-5

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