1,2-Diaryl(3-pyridyl)ethanone Oximes. Intermolecular Hydrogen Bonding Networks Revealed by X-ray Diffraction

The synthesis of a set of 1-aryl-2-aryl(3-pyridyl)ethanones 1-5 and the corresponding ketoximes 6-9 is reported. Structural studies of oximes 6, 7 and 9 were performed in solution using (1)H-NMR and in the solid state by X-ray crystallography, providing evidence of H-bonding networks. The crystal pa...

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Detalles Bibliográficos
Autores principales: Alcalde, Ermitas, Mesquida, Neus, Alvarez-Rúa, Carmen, Cuberes, Rosa, Frigola, Jordi, García-Granda, Santiago
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2008
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6245074/
https://www.ncbi.nlm.nih.gov/pubmed/18305419
http://dx.doi.org/10.3390/molecules13020301
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author Alcalde, Ermitas
Mesquida, Neus
Alvarez-Rúa, Carmen
Cuberes, Rosa
Frigola, Jordi
García-Granda, Santiago
author_facet Alcalde, Ermitas
Mesquida, Neus
Alvarez-Rúa, Carmen
Cuberes, Rosa
Frigola, Jordi
García-Granda, Santiago
author_sort Alcalde, Ermitas
collection PubMed
description The synthesis of a set of 1-aryl-2-aryl(3-pyridyl)ethanones 1-5 and the corresponding ketoximes 6-9 is reported. Structural studies of oximes 6, 7 and 9 were performed in solution using (1)H-NMR and in the solid state by X-ray crystallography, providing evidence of H-bonding networks. The crystal packing was controlled by homomeric intermolecular oxime···oxime H-bond interactions for 6 and cooperative oxime···N(pyridyl) and CH/π interactions for 7 and 9.
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spelling pubmed-62450742018-11-26 1,2-Diaryl(3-pyridyl)ethanone Oximes. Intermolecular Hydrogen Bonding Networks Revealed by X-ray Diffraction Alcalde, Ermitas Mesquida, Neus Alvarez-Rúa, Carmen Cuberes, Rosa Frigola, Jordi García-Granda, Santiago Molecules Article The synthesis of a set of 1-aryl-2-aryl(3-pyridyl)ethanones 1-5 and the corresponding ketoximes 6-9 is reported. Structural studies of oximes 6, 7 and 9 were performed in solution using (1)H-NMR and in the solid state by X-ray crystallography, providing evidence of H-bonding networks. The crystal packing was controlled by homomeric intermolecular oxime···oxime H-bond interactions for 6 and cooperative oxime···N(pyridyl) and CH/π interactions for 7 and 9. MDPI 2008-02-07 /pmc/articles/PMC6245074/ /pubmed/18305419 http://dx.doi.org/10.3390/molecules13020301 Text en © 2008 by MDPI (http://www.mdpi.org). Reproduction is permitted for noncommercial purposes.
spellingShingle Article
Alcalde, Ermitas
Mesquida, Neus
Alvarez-Rúa, Carmen
Cuberes, Rosa
Frigola, Jordi
García-Granda, Santiago
1,2-Diaryl(3-pyridyl)ethanone Oximes. Intermolecular Hydrogen Bonding Networks Revealed by X-ray Diffraction
title 1,2-Diaryl(3-pyridyl)ethanone Oximes. Intermolecular Hydrogen Bonding Networks Revealed by X-ray Diffraction
title_full 1,2-Diaryl(3-pyridyl)ethanone Oximes. Intermolecular Hydrogen Bonding Networks Revealed by X-ray Diffraction
title_fullStr 1,2-Diaryl(3-pyridyl)ethanone Oximes. Intermolecular Hydrogen Bonding Networks Revealed by X-ray Diffraction
title_full_unstemmed 1,2-Diaryl(3-pyridyl)ethanone Oximes. Intermolecular Hydrogen Bonding Networks Revealed by X-ray Diffraction
title_short 1,2-Diaryl(3-pyridyl)ethanone Oximes. Intermolecular Hydrogen Bonding Networks Revealed by X-ray Diffraction
title_sort 1,2-diaryl(3-pyridyl)ethanone oximes. intermolecular hydrogen bonding networks revealed by x-ray diffraction
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6245074/
https://www.ncbi.nlm.nih.gov/pubmed/18305419
http://dx.doi.org/10.3390/molecules13020301
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