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An Efficient Synthesis of γ-Aminoacids and Attempts to Drive Its Enantioselectivity
Addition of carboxylic acid dianions to bromoacetonitrile lead, in good yields, to the corresponding γ-cyanoacids, which on hydrogenation yielded γ-aminoacids. This two step methodology improves upon previously described results. Poor e.e’s resulted from our attempts to drive the enantioselectivity...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6245315/ https://www.ncbi.nlm.nih.gov/pubmed/18463573 http://dx.doi.org/10.3390/molecules13040716 |