Diastereoselective Synthesis of Cyclopentanediols by InCl(3)/Al Mediated Intramolecular Pinacol Coupling Reaction in Aqueous Media

A “green” and practical intramolecular pinacol coupling reaction promoted by InCl(3)/Al catalysts in aqueous media has been developed. Under mild conditions, a novel class of polysubstituted cyclopentane-1,2-diols have been obtained with excellent diastereoselectivity.

Detalles Bibliográficos
Autores principales: Chen, Yunhua, Wan, Jieping, Wang, Chunyan, Sun, Cuirong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2008
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6245409/
https://www.ncbi.nlm.nih.gov/pubmed/18971861
http://dx.doi.org/10.3390/molecules13102652
Descripción
Sumario:A “green” and practical intramolecular pinacol coupling reaction promoted by InCl(3)/Al catalysts in aqueous media has been developed. Under mild conditions, a novel class of polysubstituted cyclopentane-1,2-diols have been obtained with excellent diastereoselectivity.

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