Diastereoselective Synthesis of Cyclopentanediols by InCl(3)/Al Mediated Intramolecular Pinacol Coupling Reaction in Aqueous Media

A “green” and practical intramolecular pinacol coupling reaction promoted by InCl(3)/Al catalysts in aqueous media has been developed. Under mild conditions, a novel class of polysubstituted cyclopentane-1,2-diols have been obtained with excellent diastereoselectivity.

Detalles Bibliográficos
Autores principales: Chen, Yunhua, Wan, Jieping, Wang, Chunyan, Sun, Cuirong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2008
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6245409/
https://www.ncbi.nlm.nih.gov/pubmed/18971861
http://dx.doi.org/10.3390/molecules13102652
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author Chen, Yunhua
Wan, Jieping
Wang, Chunyan
Sun, Cuirong
author_facet Chen, Yunhua
Wan, Jieping
Wang, Chunyan
Sun, Cuirong
author_sort Chen, Yunhua
collection PubMed
description A “green” and practical intramolecular pinacol coupling reaction promoted by InCl(3)/Al catalysts in aqueous media has been developed. Under mild conditions, a novel class of polysubstituted cyclopentane-1,2-diols have been obtained with excellent diastereoselectivity.
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spelling pubmed-62454092018-11-30 Diastereoselective Synthesis of Cyclopentanediols by InCl(3)/Al Mediated Intramolecular Pinacol Coupling Reaction in Aqueous Media Chen, Yunhua Wan, Jieping Wang, Chunyan Sun, Cuirong Molecules Communication A “green” and practical intramolecular pinacol coupling reaction promoted by InCl(3)/Al catalysts in aqueous media has been developed. Under mild conditions, a novel class of polysubstituted cyclopentane-1,2-diols have been obtained with excellent diastereoselectivity. MDPI 2008-10-27 /pmc/articles/PMC6245409/ /pubmed/18971861 http://dx.doi.org/10.3390/molecules13102652 Text en © 2008 by the authors. Licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Communication
Chen, Yunhua
Wan, Jieping
Wang, Chunyan
Sun, Cuirong
Diastereoselective Synthesis of Cyclopentanediols by InCl(3)/Al Mediated Intramolecular Pinacol Coupling Reaction in Aqueous Media
title Diastereoselective Synthesis of Cyclopentanediols by InCl(3)/Al Mediated Intramolecular Pinacol Coupling Reaction in Aqueous Media
title_full Diastereoselective Synthesis of Cyclopentanediols by InCl(3)/Al Mediated Intramolecular Pinacol Coupling Reaction in Aqueous Media
title_fullStr Diastereoselective Synthesis of Cyclopentanediols by InCl(3)/Al Mediated Intramolecular Pinacol Coupling Reaction in Aqueous Media
title_full_unstemmed Diastereoselective Synthesis of Cyclopentanediols by InCl(3)/Al Mediated Intramolecular Pinacol Coupling Reaction in Aqueous Media
title_short Diastereoselective Synthesis of Cyclopentanediols by InCl(3)/Al Mediated Intramolecular Pinacol Coupling Reaction in Aqueous Media
title_sort diastereoselective synthesis of cyclopentanediols by incl(3)/al mediated intramolecular pinacol coupling reaction in aqueous media
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6245409/
https://www.ncbi.nlm.nih.gov/pubmed/18971861
http://dx.doi.org/10.3390/molecules13102652
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