Structure of Supramolecular Assemblies Formed by α,δ-Tetramethylcucurbit[6]uril and 4-Nitrophenol

A host-guest assembly, [(C(40)H(44)N(24)O(12))·(C(6)H(5)NO(3))(8)·13(H(2)O)] (1), based on a partial substituted cucurbituril, α,δ-tetramethylcucurbit[6]uril (TMeQ[6]), and 4-nitrophenol was synthesized and structurally characterized by single-crystal X-ray diffraction. A combination of hydrogen-bon...

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Autores principales: Zheng, Li-Mei, Zhang, Yun-Qian, Zeng, Jin-Ping, Qiu, Yan, Yu, Da-Hai, Xue, Sai-Feng, Zhu, Qian-Jiang, Tao, Zhu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2008
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6245417/
https://www.ncbi.nlm.nih.gov/pubmed/19015621
http://dx.doi.org/10.3390/molecules13112814
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author Zheng, Li-Mei
Zhang, Yun-Qian
Zeng, Jin-Ping
Qiu, Yan
Yu, Da-Hai
Xue, Sai-Feng
Zhu, Qian-Jiang
Tao, Zhu
author_facet Zheng, Li-Mei
Zhang, Yun-Qian
Zeng, Jin-Ping
Qiu, Yan
Yu, Da-Hai
Xue, Sai-Feng
Zhu, Qian-Jiang
Tao, Zhu
author_sort Zheng, Li-Mei
collection PubMed
description A host-guest assembly, [(C(40)H(44)N(24)O(12))·(C(6)H(5)NO(3))(8)·13(H(2)O)] (1), based on a partial substituted cucurbituril, α,δ-tetramethylcucurbit[6]uril (TMeQ[6]), and 4-nitrophenol was synthesized and structurally characterized by single-crystal X-ray diffraction. A combination of hydrogen-bonding between the latticed water molecule and the hydroxyl group of 4-nitrophenol, the hydroxyl group of 4-nitrophenol and the carbonyl groups lining the portals in additon, the C-H···π interactions between the 4-nitrophenol molecules could be the driving forces of formation such an exclusion host-guest assembly.
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spelling pubmed-62454172018-11-30 Structure of Supramolecular Assemblies Formed by α,δ-Tetramethylcucurbit[6]uril and 4-Nitrophenol Zheng, Li-Mei Zhang, Yun-Qian Zeng, Jin-Ping Qiu, Yan Yu, Da-Hai Xue, Sai-Feng Zhu, Qian-Jiang Tao, Zhu Molecules Article A host-guest assembly, [(C(40)H(44)N(24)O(12))·(C(6)H(5)NO(3))(8)·13(H(2)O)] (1), based on a partial substituted cucurbituril, α,δ-tetramethylcucurbit[6]uril (TMeQ[6]), and 4-nitrophenol was synthesized and structurally characterized by single-crystal X-ray diffraction. A combination of hydrogen-bonding between the latticed water molecule and the hydroxyl group of 4-nitrophenol, the hydroxyl group of 4-nitrophenol and the carbonyl groups lining the portals in additon, the C-H···π interactions between the 4-nitrophenol molecules could be the driving forces of formation such an exclusion host-guest assembly. MDPI 2008-11-12 /pmc/articles/PMC6245417/ /pubmed/19015621 http://dx.doi.org/10.3390/molecules13112814 Text en © 2008 by the authors. Licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Zheng, Li-Mei
Zhang, Yun-Qian
Zeng, Jin-Ping
Qiu, Yan
Yu, Da-Hai
Xue, Sai-Feng
Zhu, Qian-Jiang
Tao, Zhu
Structure of Supramolecular Assemblies Formed by α,δ-Tetramethylcucurbit[6]uril and 4-Nitrophenol
title Structure of Supramolecular Assemblies Formed by α,δ-Tetramethylcucurbit[6]uril and 4-Nitrophenol
title_full Structure of Supramolecular Assemblies Formed by α,δ-Tetramethylcucurbit[6]uril and 4-Nitrophenol
title_fullStr Structure of Supramolecular Assemblies Formed by α,δ-Tetramethylcucurbit[6]uril and 4-Nitrophenol
title_full_unstemmed Structure of Supramolecular Assemblies Formed by α,δ-Tetramethylcucurbit[6]uril and 4-Nitrophenol
title_short Structure of Supramolecular Assemblies Formed by α,δ-Tetramethylcucurbit[6]uril and 4-Nitrophenol
title_sort structure of supramolecular assemblies formed by α,δ-tetramethylcucurbit[6]uril and 4-nitrophenol
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6245417/
https://www.ncbi.nlm.nih.gov/pubmed/19015621
http://dx.doi.org/10.3390/molecules13112814
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