The Synthesis of Unsubstituted Cyclic Imides Using Hydroxylamine under Microwave Irradiation†

Unsubstituted cyclic imides were synthesized from a series of cyclic anhydrides, hydroxylamine hydrochloride (NH(2)OH∙HCl), and 4-N,N-dimethylamino-pyridine (DMAP, base catalyst) under microwave irradiation in monomode and multimode microwaves. This novel microwave synthesis produced high yields of...

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Detalles Bibliográficos
Autores principales: Benjamin, Ellis, Hijji, Yousef
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2008
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6245478/
https://www.ncbi.nlm.nih.gov/pubmed/18259138
http://dx.doi.org/10.3390/molecules13010157
Descripción
Sumario:Unsubstituted cyclic imides were synthesized from a series of cyclic anhydrides, hydroxylamine hydrochloride (NH(2)OH∙HCl), and 4-N,N-dimethylamino-pyridine (DMAP, base catalyst) under microwave irradiation in monomode and multimode microwaves. This novel microwave synthesis produced high yields of the unsubstituted cyclic imides for both the monomode (61 - 81%) and multimode (84 - 97%) microwaves.

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