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2D Metal–Organic Frameworks: Ultrathin 2D Cobalt Zeolite‐Imidazole Framework Nanosheets for Electrocatalytic Oxygen Evolution (Adv. Sci. 11/2018)

In article number https://doi.org/10.1002/advs.201801029, Kolleboyina Jayaramulu, Justus Masa, Wolfgang Schuhmann, Roland A. Fischer, and co‐workers report simple and facile synthesis of cobalt‐based 2D zeolite imidazole framework nanosheets [Co‐ZIF‐9(III)] by mechano‐chemical grinding with subseque...

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Detalles Bibliográficos
Autores principales: Jayaramulu, Kolleboyina, Masa, Justus, Morales, Dulce M., Tomanec, Ondrej, Ranc, Vaclav, Petr, Martin, Wilde, Patrick, Chen, Yen‐Ting, Zboril, Radek, Schuhmann, Wolfgang, Fischer, Roland A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6247028/
http://dx.doi.org/10.1002/advs.201870072
Descripción
Sumario:In article number https://doi.org/10.1002/advs.201801029, Kolleboyina Jayaramulu, Justus Masa, Wolfgang Schuhmann, Roland A. Fischer, and co‐workers report simple and facile synthesis of cobalt‐based 2D zeolite imidazole framework nanosheets [Co‐ZIF‐9(III)] by mechano‐chemical grinding with subsequent liquid‐phase exfoliation. The resultant 2D material exhibits highly efficient oxygen evolution reaction (OER) activity under alkaline conditions, attributed to increased accessibility of redox‐active cobalt oxyhydroxide active sites with a nitrogen coordination environment N(4)CoOOH, and efficiently mimics Co‐Porphyrin electrocatalysts. [Image: see text]