Merohedral icosahedral M(48) (M = Co(II), Ni(II)) cage clusters supported by thiacalix[4]arene

Cage clusters are a discrete chemically and topologically diverse family of molecule-based functional materials. Presented here are two isostructural M(48) (M = Co(II) for LSHU01, Ni(II) for LSHU02) cage clusters with a merohedral icosahedral cage structure featuring 12 M(4)-TC4A (H(4)TC4A, p-tert-b...

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Autores principales: Geng, Dantong, Han, Xu, Bi, Yanfeng, Qin, Yucai, Li, Qiang, Huang, Liangliang, Zhou, Kun, Song, Lijuan, Zheng, Zhiping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6251337/
https://www.ncbi.nlm.nih.gov/pubmed/30568777
http://dx.doi.org/10.1039/c8sc03193b
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author Geng, Dantong
Han, Xu
Bi, Yanfeng
Qin, Yucai
Li, Qiang
Huang, Liangliang
Zhou, Kun
Song, Lijuan
Zheng, Zhiping
author_facet Geng, Dantong
Han, Xu
Bi, Yanfeng
Qin, Yucai
Li, Qiang
Huang, Liangliang
Zhou, Kun
Song, Lijuan
Zheng, Zhiping
author_sort Geng, Dantong
collection PubMed
description Cage clusters are a discrete chemically and topologically diverse family of molecule-based functional materials. Presented here are two isostructural M(48) (M = Co(II) for LSHU01, Ni(II) for LSHU02) cage clusters with a merohedral icosahedral cage structure featuring 12 M(4)-TC4A (H(4)TC4A, p-tert-butylthiacalix[4]arene) second building units as vertices and 18 asymmetric 5-(1H-tetrazol-1-yl)isophthalate ligands as faces. They are the highest-nuclearity cage compounds of Co(II) and Ni(II). The activated Co(48) cage exhibited high selectivity in the sorption of C(3)H(8) over CH(4) under ambient conditions. Frequency response experiments indicated that the extrinsic voids and matrix interface of the activated crystalline samples are primarily responsible for the observed gas adsorption performance.
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spelling pubmed-62513372018-12-19 Merohedral icosahedral M(48) (M = Co(II), Ni(II)) cage clusters supported by thiacalix[4]arene Geng, Dantong Han, Xu Bi, Yanfeng Qin, Yucai Li, Qiang Huang, Liangliang Zhou, Kun Song, Lijuan Zheng, Zhiping Chem Sci Chemistry Cage clusters are a discrete chemically and topologically diverse family of molecule-based functional materials. Presented here are two isostructural M(48) (M = Co(II) for LSHU01, Ni(II) for LSHU02) cage clusters with a merohedral icosahedral cage structure featuring 12 M(4)-TC4A (H(4)TC4A, p-tert-butylthiacalix[4]arene) second building units as vertices and 18 asymmetric 5-(1H-tetrazol-1-yl)isophthalate ligands as faces. They are the highest-nuclearity cage compounds of Co(II) and Ni(II). The activated Co(48) cage exhibited high selectivity in the sorption of C(3)H(8) over CH(4) under ambient conditions. Frequency response experiments indicated that the extrinsic voids and matrix interface of the activated crystalline samples are primarily responsible for the observed gas adsorption performance. Royal Society of Chemistry 2018-09-12 /pmc/articles/PMC6251337/ /pubmed/30568777 http://dx.doi.org/10.1039/c8sc03193b Text en This journal is © The Royal Society of Chemistry 2018 http://creativecommons.org/licenses/by/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (CC BY 3.0)
spellingShingle Chemistry
Geng, Dantong
Han, Xu
Bi, Yanfeng
Qin, Yucai
Li, Qiang
Huang, Liangliang
Zhou, Kun
Song, Lijuan
Zheng, Zhiping
Merohedral icosahedral M(48) (M = Co(II), Ni(II)) cage clusters supported by thiacalix[4]arene
title Merohedral icosahedral M(48) (M = Co(II), Ni(II)) cage clusters supported by thiacalix[4]arene
title_full Merohedral icosahedral M(48) (M = Co(II), Ni(II)) cage clusters supported by thiacalix[4]arene
title_fullStr Merohedral icosahedral M(48) (M = Co(II), Ni(II)) cage clusters supported by thiacalix[4]arene
title_full_unstemmed Merohedral icosahedral M(48) (M = Co(II), Ni(II)) cage clusters supported by thiacalix[4]arene
title_short Merohedral icosahedral M(48) (M = Co(II), Ni(II)) cage clusters supported by thiacalix[4]arene
title_sort merohedral icosahedral m(48) (m = co(ii), ni(ii)) cage clusters supported by thiacalix[4]arene
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6251337/
https://www.ncbi.nlm.nih.gov/pubmed/30568777
http://dx.doi.org/10.1039/c8sc03193b
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