X-ray and Hydrogen-bonding Properties of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol

The solid state structure of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol, C(17)H(13)N(3)O, shows that this Mannich base crystallizes forming intermolecular N⋯HO hydrogen bonds, rather than intramolecular ones. Factors contributing to this choice of hydrogen-bonding mode are discussed. The compou...

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Detalles Bibliográficos
Autores principales: Rivera, Augusto, Duarte, Yorley, González-Salas, Diego, Ríos-Motta, Jaime, Zaragoza, Guillermo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2009
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6253878/
https://www.ncbi.nlm.nih.gov/pubmed/19325520
http://dx.doi.org/10.3390/molecules14031234
Descripción
Sumario:The solid state structure of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol, C(17)H(13)N(3)O, shows that this Mannich base crystallizes forming intermolecular N⋯HO hydrogen bonds, rather than intramolecular ones. Factors contributing to this choice of hydrogen-bonding mode are discussed. The compound crystallizes in the monoclinic system, P2(1)/c space group, with lattice constants: a = 11.7934(9) Å, b = 14.3002(14) Å, c = 8.4444(8) Å, β = 106.243(5) deg, V = 1367.3(2) Å(3), Z = 4, F(000) = 576, R(1) = 6.96%, wR(2) = 11.4%.

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