X-ray and Hydrogen-bonding Properties of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol

The solid state structure of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol, C(17)H(13)N(3)O, shows that this Mannich base crystallizes forming intermolecular N⋯HO hydrogen bonds, rather than intramolecular ones. Factors contributing to this choice of hydrogen-bonding mode are discussed. The compou...

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Autores principales: Rivera, Augusto, Duarte, Yorley, González-Salas, Diego, Ríos-Motta, Jaime, Zaragoza, Guillermo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2009
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6253878/
https://www.ncbi.nlm.nih.gov/pubmed/19325520
http://dx.doi.org/10.3390/molecules14031234
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author Rivera, Augusto
Duarte, Yorley
González-Salas, Diego
Ríos-Motta, Jaime
Zaragoza, Guillermo
author_facet Rivera, Augusto
Duarte, Yorley
González-Salas, Diego
Ríos-Motta, Jaime
Zaragoza, Guillermo
author_sort Rivera, Augusto
collection PubMed
description The solid state structure of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol, C(17)H(13)N(3)O, shows that this Mannich base crystallizes forming intermolecular N⋯HO hydrogen bonds, rather than intramolecular ones. Factors contributing to this choice of hydrogen-bonding mode are discussed. The compound crystallizes in the monoclinic system, P2(1)/c space group, with lattice constants: a = 11.7934(9) Å, b = 14.3002(14) Å, c = 8.4444(8) Å, β = 106.243(5) deg, V = 1367.3(2) Å(3), Z = 4, F(000) = 576, R(1) = 6.96%, wR(2) = 11.4%.
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spelling pubmed-62538782018-11-30 X-ray and Hydrogen-bonding Properties of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol Rivera, Augusto Duarte, Yorley González-Salas, Diego Ríos-Motta, Jaime Zaragoza, Guillermo Molecules Article The solid state structure of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol, C(17)H(13)N(3)O, shows that this Mannich base crystallizes forming intermolecular N⋯HO hydrogen bonds, rather than intramolecular ones. Factors contributing to this choice of hydrogen-bonding mode are discussed. The compound crystallizes in the monoclinic system, P2(1)/c space group, with lattice constants: a = 11.7934(9) Å, b = 14.3002(14) Å, c = 8.4444(8) Å, β = 106.243(5) deg, V = 1367.3(2) Å(3), Z = 4, F(000) = 576, R(1) = 6.96%, wR(2) = 11.4%. Molecular Diversity Preservation International 2009-03-23 /pmc/articles/PMC6253878/ /pubmed/19325520 http://dx.doi.org/10.3390/molecules14031234 Text en © 2009 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Rivera, Augusto
Duarte, Yorley
González-Salas, Diego
Ríos-Motta, Jaime
Zaragoza, Guillermo
X-ray and Hydrogen-bonding Properties of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol
title X-ray and Hydrogen-bonding Properties of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol
title_full X-ray and Hydrogen-bonding Properties of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol
title_fullStr X-ray and Hydrogen-bonding Properties of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol
title_full_unstemmed X-ray and Hydrogen-bonding Properties of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol
title_short X-ray and Hydrogen-bonding Properties of 1-((1H-benzotriazol-1-yl)methyl)naphthalen-2-ol
title_sort x-ray and hydrogen-bonding properties of 1-((1h-benzotriazol-1-yl)methyl)naphthalen-2-ol
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6253878/
https://www.ncbi.nlm.nih.gov/pubmed/19325520
http://dx.doi.org/10.3390/molecules14031234
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