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Synthesis and Analysis of Resorcinol-Acetone Copolymer
Synthesis and characterization of resorcinol-acetone copolymer is described. The polymer was prepared by trifluoroacetic acid-catalyzed polymerization of resorcinol with acetone. According to the (1)H-NMR, (13)C-NMR, and MALDI-TOF Mass spectra data, the obtained polymer had three types of repeating...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Molecular Diversity Preservation International
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6253941/ https://www.ncbi.nlm.nih.gov/pubmed/19145215 http://dx.doi.org/10.3390/molecules14010364 |
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author | Kobayashi, Ataru Konishi, Gen-ichi |
author_facet | Kobayashi, Ataru Konishi, Gen-ichi |
author_sort | Kobayashi, Ataru |
collection | PubMed |
description | Synthesis and characterization of resorcinol-acetone copolymer is described. The polymer was prepared by trifluoroacetic acid-catalyzed polymerization of resorcinol with acetone. According to the (1)H-NMR, (13)C-NMR, and MALDI-TOF Mass spectra data, the obtained polymer had three types of repeating units: isopropylidene bridged-resorcinol, chromane ring, and spiro-shaped double chromane ring, indicating that polymerization proceeded via simultaneous addition-condensation and cyclization of resorcinol with acetone. The obtained polymer can be useful not only for the development of plastic materials such as thermosets, adhesives, and coatings but also for the synthesis of biomaterials such as antimicrobial agents, pesticides, and medicines. |
format | Online Article Text |
id | pubmed-6253941 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | Molecular Diversity Preservation International |
record_format | MEDLINE/PubMed |
spelling | pubmed-62539412018-11-30 Synthesis and Analysis of Resorcinol-Acetone Copolymer Kobayashi, Ataru Konishi, Gen-ichi Molecules Article Synthesis and characterization of resorcinol-acetone copolymer is described. The polymer was prepared by trifluoroacetic acid-catalyzed polymerization of resorcinol with acetone. According to the (1)H-NMR, (13)C-NMR, and MALDI-TOF Mass spectra data, the obtained polymer had three types of repeating units: isopropylidene bridged-resorcinol, chromane ring, and spiro-shaped double chromane ring, indicating that polymerization proceeded via simultaneous addition-condensation and cyclization of resorcinol with acetone. The obtained polymer can be useful not only for the development of plastic materials such as thermosets, adhesives, and coatings but also for the synthesis of biomaterials such as antimicrobial agents, pesticides, and medicines. Molecular Diversity Preservation International 2009-01-13 /pmc/articles/PMC6253941/ /pubmed/19145215 http://dx.doi.org/10.3390/molecules14010364 Text en © 2009 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/). |
spellingShingle | Article Kobayashi, Ataru Konishi, Gen-ichi Synthesis and Analysis of Resorcinol-Acetone Copolymer |
title | Synthesis and Analysis of Resorcinol-Acetone Copolymer |
title_full | Synthesis and Analysis of Resorcinol-Acetone Copolymer |
title_fullStr | Synthesis and Analysis of Resorcinol-Acetone Copolymer |
title_full_unstemmed | Synthesis and Analysis of Resorcinol-Acetone Copolymer |
title_short | Synthesis and Analysis of Resorcinol-Acetone Copolymer |
title_sort | synthesis and analysis of resorcinol-acetone copolymer |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6253941/ https://www.ncbi.nlm.nih.gov/pubmed/19145215 http://dx.doi.org/10.3390/molecules14010364 |
work_keys_str_mv | AT kobayashiataru synthesisandanalysisofresorcinolacetonecopolymer AT konishigenichi synthesisandanalysisofresorcinolacetonecopolymer |