Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): Efficient Catalysts for the Cyanosilylation and Cyanocarbonation of Aldehydes and Ketones

A variety of aldehydes and ketones were transformed to their corresponding cyanohydrin silyl ethers in good to excellent yields in the presence of 1-5 mol% of tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP). Cyanohydrin carbonates were also readily prepared using 5-10 mol% of TTMPP as an organocatalys...

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Detalles Bibliográficos
Autores principales: Matsukawa, Satoru, Sekine, Izumi, Iitsuka, Ayumi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2009
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6254716/
https://www.ncbi.nlm.nih.gov/pubmed/19783929
http://dx.doi.org/10.3390/molecules14093353
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author Matsukawa, Satoru
Sekine, Izumi
Iitsuka, Ayumi
author_facet Matsukawa, Satoru
Sekine, Izumi
Iitsuka, Ayumi
author_sort Matsukawa, Satoru
collection PubMed
description A variety of aldehydes and ketones were transformed to their corresponding cyanohydrin silyl ethers in good to excellent yields in the presence of 1-5 mol% of tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP). Cyanohydrin carbonates were also readily prepared using 5-10 mol% of TTMPP as an organocatalyst.
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spelling pubmed-62547162018-11-30 Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): Efficient Catalysts for the Cyanosilylation and Cyanocarbonation of Aldehydes and Ketones Matsukawa, Satoru Sekine, Izumi Iitsuka, Ayumi Molecules Article A variety of aldehydes and ketones were transformed to their corresponding cyanohydrin silyl ethers in good to excellent yields in the presence of 1-5 mol% of tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP). Cyanohydrin carbonates were also readily prepared using 5-10 mol% of TTMPP as an organocatalyst. Molecular Diversity Preservation International 2009-09-02 /pmc/articles/PMC6254716/ /pubmed/19783929 http://dx.doi.org/10.3390/molecules14093353 Text en © 2009 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Matsukawa, Satoru
Sekine, Izumi
Iitsuka, Ayumi
Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): Efficient Catalysts for the Cyanosilylation and Cyanocarbonation of Aldehydes and Ketones
title Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): Efficient Catalysts for the Cyanosilylation and Cyanocarbonation of Aldehydes and Ketones
title_full Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): Efficient Catalysts for the Cyanosilylation and Cyanocarbonation of Aldehydes and Ketones
title_fullStr Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): Efficient Catalysts for the Cyanosilylation and Cyanocarbonation of Aldehydes and Ketones
title_full_unstemmed Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): Efficient Catalysts for the Cyanosilylation and Cyanocarbonation of Aldehydes and Ketones
title_short Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): Efficient Catalysts for the Cyanosilylation and Cyanocarbonation of Aldehydes and Ketones
title_sort tris(2,4,6-trimethoxyphenyl)phosphine (ttmpp): efficient catalysts for the cyanosilylation and cyanocarbonation of aldehydes and ketones
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6254716/
https://www.ncbi.nlm.nih.gov/pubmed/19783929
http://dx.doi.org/10.3390/molecules14093353
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AT iitsukaayumi tris246trimethoxyphenylphosphinettmppefficientcatalystsforthecyanosilylationandcyanocarbonationofaldehydesandketones

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