Synthesis and Characterization of Some Chiral Metal-Salen Complexes Bearing a Ferrocenophane Substituent

The C(2)-symmetrical “salen” ligand (+)-9 bearing two [5]ferrocenophane substituents has been prepared in five steps starting from readily available diacetylferrocene, p-hydroxybenzaldehyde and (R,R)-N,N’-diphenylethylenediamine. Reaction of (+)-9 with Mn(OAc)(3), Co(OAc)(2) ZnEt(2) or UO(2)(OAc)(2)...

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Autores principales: Patti, Angela, Pedotti, Sonia, Ballistreri, Francesco Paolo, Sfrazzetto, Giuseppe Trusso
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Molecular Diversity Preservation International 2009
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6254795/
https://www.ncbi.nlm.nih.gov/pubmed/19924066
http://dx.doi.org/10.3390/molecules14114312
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author Patti, Angela
Pedotti, Sonia
Ballistreri, Francesco Paolo
Sfrazzetto, Giuseppe Trusso
author_facet Patti, Angela
Pedotti, Sonia
Ballistreri, Francesco Paolo
Sfrazzetto, Giuseppe Trusso
author_sort Patti, Angela
collection PubMed
description The C(2)-symmetrical “salen” ligand (+)-9 bearing two [5]ferrocenophane substituents has been prepared in five steps starting from readily available diacetylferrocene, p-hydroxybenzaldehyde and (R,R)-N,N’-diphenylethylenediamine. Reaction of (+)-9 with Mn(OAc)(3), Co(OAc)(2) ZnEt(2) or UO(2)(OAc)(2) gave the corresponding metal-complexes which were characterised by spectroscopic methods.
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spelling pubmed-62547952018-11-30 Synthesis and Characterization of Some Chiral Metal-Salen Complexes Bearing a Ferrocenophane Substituent Patti, Angela Pedotti, Sonia Ballistreri, Francesco Paolo Sfrazzetto, Giuseppe Trusso Molecules Article The C(2)-symmetrical “salen” ligand (+)-9 bearing two [5]ferrocenophane substituents has been prepared in five steps starting from readily available diacetylferrocene, p-hydroxybenzaldehyde and (R,R)-N,N’-diphenylethylenediamine. Reaction of (+)-9 with Mn(OAc)(3), Co(OAc)(2) ZnEt(2) or UO(2)(OAc)(2) gave the corresponding metal-complexes which were characterised by spectroscopic methods. Molecular Diversity Preservation International 2009-10-26 /pmc/articles/PMC6254795/ /pubmed/19924066 http://dx.doi.org/10.3390/molecules14114312 Text en © 2009 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/3.0/).
spellingShingle Article
Patti, Angela
Pedotti, Sonia
Ballistreri, Francesco Paolo
Sfrazzetto, Giuseppe Trusso
Synthesis and Characterization of Some Chiral Metal-Salen Complexes Bearing a Ferrocenophane Substituent
title Synthesis and Characterization of Some Chiral Metal-Salen Complexes Bearing a Ferrocenophane Substituent
title_full Synthesis and Characterization of Some Chiral Metal-Salen Complexes Bearing a Ferrocenophane Substituent
title_fullStr Synthesis and Characterization of Some Chiral Metal-Salen Complexes Bearing a Ferrocenophane Substituent
title_full_unstemmed Synthesis and Characterization of Some Chiral Metal-Salen Complexes Bearing a Ferrocenophane Substituent
title_short Synthesis and Characterization of Some Chiral Metal-Salen Complexes Bearing a Ferrocenophane Substituent
title_sort synthesis and characterization of some chiral metal-salen complexes bearing a ferrocenophane substituent
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6254795/
https://www.ncbi.nlm.nih.gov/pubmed/19924066
http://dx.doi.org/10.3390/molecules14114312
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